Pre-lecture problems: Oxidation and reduction HO H Ag(NO3)2, NaOH HO KMnO4 Ag(NO3)2, NaOH ОН KMnO4 HO H o
(10 pts) Predict the major product for each of the following reactions. 2. Ho Br 1. NaOH/Br 2. H,O NaOH/H20 1. NaOCH,CH 2. H,0 1. NaOCH,CH, 2 HO
(10 pts) Predict the major product for each of the following reactions. 2. Ho Br 1. NaOH/Br 2. H,O NaOH/H20 1. NaOCH,CH 2. H,0 1. NaOCH,CH, 2 HO
2. Write the major and minor products for each reaction. tBuOK H,SO Heat NaOH HO NaOH HO
H,SO HO 1. BHTHF 2. HẠO, NaOH ou H,SO H0 1. Hg(OAc),,H,O 2. NaBH H.PO H.0 Draw the mechanisms of each of the reactions including all electrons and arrow pushing
bbb.) Cl2 FeBrz HO CCC.) H 1. KMnO4/NaOH(aq)/A 2. H307 ddd.) CN oleum eee.) NO2 1. Sn, HCI, A 2. HNO2, HCI 3. HBF4 H fff) Hz. Pd 4500 psi 999) OH 1. XS KMnO, NaOH(aq) 2. H,09 hhh.) 1. PrLI, THF 2. NHCl(aq) 1.) CH,BF4 Br SO,/H,SO 1.04. CHÚCOH 2. HO 11.) -Br 1. Mg/THF 2. HO
2) What is the product of the following reactions [8 Points] HO 1) NaOH 2)CH3Li 3)H*, H20 1) CH31 (Excess) 2) Ag20 3) Heat 1) LDA 2) CH3Br
2) What is the product of the following reactions [8 Points) HO 1) NaOH 2)CH2Li 3)H+, H20 OH 1) CH3I (Excess) 2) Ag20 3) Heat 1) LDA 2) CH2Br
7. 8. Na2SO3 + HCI — K,CrO4 + Pb(NO3)2 —> NaC,H,O, + HCl — NaOH + NH4NO3 → 09HHH - .100 ,00 HO, 00 → BiClg + H2S Dan 13. | 14. 15. K,C,04 + HCI — H,PO, + Ca(OH)2 — (NH) CO, + HNO3 - K.CO, + NiBr-
1. SOCI2 2. CH3NH2 3. LiAIHA 4. H20* O glo OH O H Br
1. NaOCH,CH, 2. HO, HP CH,NO NaOH 1. CH,ON, CH OH 2. HẠO, H" 3. heat 1. N.NO, HCI 1.H.O. 2 heat NICH