



The circled one is the Diastereomer which will give D-threose.
In addition to threose, eyrthose is also formed.
5. Demonstrate the Kiliani-Fischer procedure on the example of conversion of D- glyceraldehyde into D-threose. CHO...
The corresponding structure is: Glyceraldehyde is an aldose monosaccharide. The Fischer projection of D-glyceraldehyde is shown. HO o OH OH HCOH Hпин-Синон HOH CH2OH D-glyceraldehyde H2-OH HCOH O OLHO OH Translate the Fischer projection to show D-glyceraldehyde with wedge and dash bonds. Hi.... C OH HC-OH H₂Ē -oh HO-OH 8 9 RUOP
Drawings Instructor's approval of models L-glyceraldehyde Fischer: L-glyceraldehyde Fischer: D-glyceraldehyde H C Hico OH-c-H D-glyceraldehyde H-6-oh CH2OH CH2OH Fischer: L-glucose Fischer: D-glucose D-glucose Haworth: C-D-glucose Haworth: -D-glucose CE-D-glucose
Chapter 25: Reactions & Linkages Name: 1. If D-ribose underwent the Kiliani-Fischer synthesis (chain lengthening), what two new sugars would be produced. Draw the Fischer projections of the new sugars. CHO Н. OH Kiliani-Fischer H OH Synthesis H -OH CH2OH D-Ribose
5. Convert the following Fischer projection to a pyranose). CHO HOH но-н H- H НЕОН CH2OH acyclic pyranose scaffold a-pyranose Haworth
Glyceraldehyde is an aldose monosaccharide. The Fischer projection of D-glyceraldehyde is shown. Draw D-glyceraldehyde using wedge and dash bonds around the chirality center. Include all hydrogen atoms.
10. Which Fischer projection corresponds with the following molecule? Br CHO CHO CHO СНО CHO OHHO- HOH HOB HO- - Br H Br Br Br CH.CH CH2CHE CH2CH3 CH2CH) CH2CHE III IV TIT II d. IV e. V b.
QUESTION 9 In the Fischer projection of Glyceraldehyde shown below, CHO - H-C-OH - CH2OH The molecule is in the D-form The molecule in the L-form The-CHO group is facing forward The H group is facing backward, QUESTION 10 In O-linked and N-linked transmembrane glycoproteins, The side chains of amino acids present on the outside of the membrane are glycosylated The back-bone-NH and Co groups of amino acids present on the inside of the membrane are glycosylated. The side chains...
Catch Report Sheer - Lab 16 Date Neotion Instructor A. Al Monosaceharides Fischer projections L-glyceraldehyde D-glyceraldehyde How does L-glyceraldehyde differ from D-glyceraldehyde? A.2 Fischer projection of D-glucose Haworth (cyclic) formulas a-D-glucose B-D-glucose Haworth (cyclic) formula for a-D-fructose A.3 Fischer projection of D-fructose
CARBOHYDRATES POST-LAB QUESTIONS [52] 19. Review the Fischer structures of D-galactose, D-glucose, and D-mannose Identify each structure. [12 pts) CHO CHO CHO Н. -OH HO -H H -OH HO -H HO H HO -H Н. OH H OH HO -H H -OH H ОН Н. ОН CH2OH CH2OH CH2OH D-Glucose D-Mannose TD-Galactose 20. Would either D-galactose or D-mannose form an osazone identical to the glucose osazone? [5 pts] 21. Explain: [5 pts) [5 pts] 22. What structural feature do all...
3) a) Draw the Fischer projection of the following sugars and
label them D or L. HO
b) Draw the most stable chair conformation of the b-anomer of the
hemiacetal of the following
aldohexose:
3) a) Draw the Fischer projection of the following sugars and label them Dor L. НО. H CHO он НО H он Н. ОН НО. CHO ли нон н он b) Draw the most stable chair conformation of the B-anomer of the hemiacetal of the following...