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Part C. Effect of Concentration on Cell Potentials • Ecall for the Cu(s). Cu2+||Ag*, Ag(s) system:...
Compare the potentials between the Ag/Ag+ and Cu/Cu2+ half cells before and after adding excess NH3 to the Cu/Cu2+ half cell. Did the potential increase or decrease? Explain the result in terms of the Nernst equation.
Identify the complete redox reaction for a CulCu2+||Ag+Ag cell. A. Cu(s) + Ag(s) Cu2+ (aq) + Ag+ (aq) B. Cu(s) + Ag+ (aq) + Cu2+ (aq) + Ag(s) c. Cu(s) + 2 Ag+ (aq) (aq) + 2 Ag(s) D. Cu²+ (aq) + 2 Ag(s) + Cu(s) + 2 Ag+ (aq) → Cu2+
11. Write the balanced redox reaction corresponding to the following cell diagram: Cu(s) / Cu2+ ( 1M) || Ag+ (1M) / Ag(s)
Use the table of Standdard Reduction Potentials and the Nernst
Equation to calculate the concentration of Cu2+ present in the
Cu/Cu2+ half-cell after the addition NH3 (aq) while it was coupled
with
a) Zn/Zn2+
b) Ag/Ag+
Table 2 has your measured voltages for these cells. SHOW YOUR
SETUP OF THE NERST EQUATION WITH ALL VARIABLES FILLED IN. SHOW THE
CALCULATED [Cu2+] CONCENTRATION.
Table 2:
METAL
Mg
Ag
Ni
Zn
Pb
Cu
1.230 V
0.642 V
0.030 V
0.648 V
0.256...
During part B of your lab, you measured electrochemical cell potentials with a Cu2+/Cu couple as the anode. Predict the results you would observe if Ag+/Ag were the anode. half-cell predicted potential difference in V Cu2+/Cu Ag+/Ag Pb2+/Pb Zn2+/Zn
During part B of your lab, you measured electrochemical cell potentials with a Cu2+/Cu couple as the anode. Predict the results you would observe if Ag+/Ag were the anode. half-cell predicted potential difference in V Cu2+/Cu Ag+/Ag Pb2+/Pb Zn2+/Zn
Calculate the E°cell for the following reaction: Cu2+ (aq) + Ni (s) → Cu (s) + Ni2+ (aq) A) (-0.59 ± 0.01) V B) (-0.09 ± 0.01) V C) (0.59 ± 0.01) V D) (0.09 ± 0.01) V --------------------------------------------------------------------------------------------------------- What is the proper line notation for the following reaction? Cu (s) + 2Ag+ (aq) → Cu2+ (aq) + 2Ag (s) A) Cu2+ | Cu || Ag | Ag+ B) Ag+ | Ag || Cu | Cu2+ C) Cu |...
Suppose a concentration cell of: Cu(s) | Cu2+(dilute) || Cu2+(concentrated)| Cu(s) is made with the following concentrations: Dilute: Cu2+ = 2.5 x 10-4 Concentrated: Cu2+ = 5.0 x 10-2 What will be the cell potential of the cell? 0.084 V 0.0 V 0.030 V 0 0.013 V
cell A voltaic cell employs the following redox reaction: Cu(s) + 2 Ag+ (aq) – Cu 2+ (aq) + 2 Ag(s) The E° for the reaction is +0.46 V. The initial (nonstandard) conditions are: [Ag +] = 0.025M; [Cu 2+] = 2.0 M Part a. Write the half-reaction that occurs at the anode. Part b. Write the half-reaction that occurs at the cathode. Part c. How many electrons are transferred in this reaction? Part d. What is the cell potential,...
Calculate the E°cell for the following reaction: Cu2+ (aq) + Ni (s) → Cu (s) + Ni2+ (aq) A) (-0.59 ± 0.01) V B) (-0.09 ± 0.01) V C) (0.59 ± 0.01) V D) (0.09 ± 0.01) V --------------------------------------------------------------------------------------------------------- What is the proper line notation for the following reaction? Cu (s) + 2Ag+ (aq) → Cu2+ (aq) + 2Ag (s) A) Cu2+ | Cu || Ag | Ag+ B) Ag+ | Ag || Cu | Cu2+ C) Cu |...