ΔTf = i*Kf*m
ΔTf is the depression in freezing point
ΔTf will be maximum when i is maximum Since molality, m is same for all.
so, lowest freezing point is for that solution which has higher value of i
i for BaCl2 is 3 as it dissociates into 1 Ba2+ and 2 Cl-
CO(NH2)2 is non electrolyte. So, i=1
i for CaSO4 is 2
i for NH4NO3 is 2
i for CH3COOH is less than 2 as it is weak electrolyte.
i is maximum for BaCl2.
So, it will have lowest freezing point
Answer: a
steps of solving please 33. Which of the following solutes, dissolved in 1000 g of water,...
Which of the following solutes, dissolved in 1000 g of water, would provide a solution with the lowest freezing point? 0.045 mol of barium chloride, MgCl2 0.045 mol of ammonium nitrate, NH Br 0.045 mol of acetic acid, CH3COOH 0.045 mol of urea, CO(CH3)2 0.045 mol of calcium sulfate, BaSO4
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Which of the following aqueous solutions are good buffer systems? 0.14 M acetic acid + 0.20 M potassium acetate 0.16 M calcium hydroxide + 0.22 M calcium bromide 0.29 M hydrobromic acid + 0.16 M potassium bromide 0.33 M ammonia + 0.32 M ammonium nitrate 0.38 M barium chloride + 0.26 M barium perchlorate A buffer solution is made that is 0.320 M in...
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Experiment 8 Name: Double Replacement Reactions Background: Some reactions have the net effect of causing the cation of cach reactant to trade places, forming a compound with the other anion. These reactions are known as double replacement reactions. In the example below (unbalanced equation), the barium and sodium cations switch places so that barium forms a product with sulfate while sodium forms...
Experiment 8 Double Replacement Reactions Background: Some reactions have the net effect of causing the cation of each reactant to trade places, forming a compound with the other anion. These reactions are known as double replacement reactions. In the example below (unbalanced equation), the barium and sodium cations switch places so that barium forms a product with sulfate while sodium forms a product with chloride. Note that the formula of each product is determined by the charges of the ions,...
Spring 2019 CSUSM CHEM 175 8. Which statements are true? Select ALL. that apply. a) Dissolution of ammonium nitrate is an endothermic reactio b) Hydrogen gas evolves when calcium carbonate reacts with hydrochloric acid. c) The acid-base neutralization reaction is exothermic. ) The value of enthalpy change, AH, of calcium chloride dissolution is positive. sample contains an unknown amount of Fe?'which is titrated with a KMnO, solution in acidie tions to determine the iron composition by mass. A standardized KMnOs...
4.30. Using solubility rules, predict the solubility in water of the following ionic compounds. a. AI(OH) b. CaN C. NH4CI d. KOH 4.32. Using solubility rules, decide whether the following ionic solids are soluble or insoluble in water. If they are soluble, write the chemical equation for dissolving in water and indicate what ions you would expect to be present in solution. (NE SO b. BaCO c. Pb(NOs)2 d. Ca(OH) 4.34. Write net ionic equations for the following molecular equations....
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Unless otherwise specified in the problem, you may assume that all solutions are at 25°C. 1. 50.0 mL of a pH 6.00 carbonic acid buffer is titrated with 0.2857 M NaOH, requiring 17.47 mL to reach the second equivalence point. a. Calculate the molarity of carbonic acid and bicarbonate in the original buffer. Carbonic acid: Bicarbonate: b. Calculate the pH of the solution after a total of 100.0 mL of 0.2857...
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15. Which of the following mixtures would result in a buffered solution? a. Mixing 100.0 mL of 0.100 M HCl with 100.0 mL of 0.100 M NaOH. b. Mixing 100.0 mL of 0.100 M NH3 (K5=1.8 x 10-5) with 100.0 mL of 0.100 M NaOH. c. Mixing 100.0 mL of 0.100 M HCl with 100.0 mL of 0.100 M NH; (K =18x 10 %. d. Mixing 50.0 mL of 0.100 M HCl with...
1) A solution contains 0.14 M potassium hydroxide and 0.14 M potassium chloride. Solid silver acetate is added slowly to this mixture. What ionic compound precipitates first from the solution? (Solubility product constant data is found in the Chemistry References.) Formula of first precipitate = 2) A solution contains 5.12×10-3 M chromium(III) nitrate and 1.22×10-2 M calcium acetate. Solid sodium phosphate is added slowly to this mixture. A. What is the formula of the substance that precipitates first? formula =...
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1. Acetic acid (H)CO2H) has k, = 1.8 x 10- and acetate (H:C:01") has ks = 5.6 x 10-10. (a) Write balanced chemical equilibrium equations (with physical states) for acid dissociation of acetic acid and base hydrolysis of acetate ion. (b) Write K, and equilibrium constant expressions for the above reactions. (c) Use your expressions from part b to show that Kx. = 1.0 x 10-* = [H,O'][OH). 2. For each...