Question

How do the d orbitals split in each of the following complexes? (a) [Ni(CN)s]s with Dan Symmetry (c) [PtCla]2 with Dan Symmet
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Answer #1

C3 N3 111 c1 12

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Cui Br4

[Ni(CN)5]3-

[Ni(CN)5]3-

[PtCl4]2+

[CuBr4]+

D3h

C4v

D4h

Td

Trigonal bipyramidal

Square pyramidal

Square planar

tetrahedral

d8(low spin)

d8(low spin)

d8(high spin)

d10(high spin)

trigonal bipyramidal d orbital splitting

dz2 dx2-y2 dxy dxz dyz

square pyramidal d orbital splitting

dx2-y2 zzp dxy zxp záp

square planar d orbital splitting

dx2-y2 dxy dz2 dxz dyz

tetrahedral

dxy dyz dzx dx2-y2 dz2

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