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Write out the product for each of the following reactions. NaOH oltz Heat H+ B) Nott...
b) Write a structural formula for the principal organic
product(s) of each of the following reactions
b) Write a structural formula for the principal organic product(s) of each of the following reactions CH3NH2 NaOH CH3CH2OH H2SO4 OH SOCI pyridine 1. CH3 MgBr(xs) Et, 2. H30
II. Draw the structure for the major organic product of each of the following reactions. (7.5 pts each, 45 pts) Ç(CH3) 30 1) PhČCI, AICI: 11. 2) Et2NH, H2, Raney-Ni, heat 12. ÇO,Me 1) EtMgBr (2 equiv.) 2) H20, H30* O 13. CNH2 1) Bry, NaOH, H,0 O 2) (CH3)2CHCCI, pyridine 14. Brą, H20 CHO HOEH H HOH НЕОН HO+H CH OH 15. H2N. ***** оо CO2 1) (CH3),COCOCOC(CH3)3 2) -N: C: NH- 16. CHO нон PhNHNH2 H+OH (3 equiv.)...
4. Synthesis Reactions. Draw the feature product of the following reactions. (8 x 3 pts) 1. Mg Ph Br 2. CO2 3. H a "NH2 Ph 1. NaOH, CI 2. LAIH b. CHỊCH NHA NaBHgCN, H+ Ph C. Br (excess) NH d NaOH H HO OH H CH e. 1. NaOH H2O NH 2. H+ o= 1. NaOH H2O 2. SOCI N(CH3)2 3 HO
II. Draw the structure for the major organic product of each of the following reactions. 11. Ç(CH3) 30 1) PhČCI, AICI: 2) Et2NH, H2, Raney-Ni, heat 12. ÇO2Me 1) EtMgBr (2 equiv.) 2) H20, H30+ 13. o CNH2 1) Br2, NaOH, H20 O 2) (CH3)2CHČCI, pyridine 14. Br2, H20 CHO HOEH H -OH H-OH HOEH CH2OH
II. Draw the structure for the major organic product of each of the following reactions. (7.5 pts each, 45 pts) Ç(CH3)3 o 11. 1) PhČCI, AICI 2) EtANH, H2, Raney-Ni, heat 12. ÇO Me 1) EtMgBr (2 equiv.) 2) H20, H30* 13. o CNH2 1) Brą, NaOH, H20 o 2) (CH3)2CHCCI, pyridine 14. CHO HO+H H-OH Br2, H20 H-HOH HO+H CH2OH
1(10) Complete the following reactions. Label the major product if there is more than one product CH₃ CH₂ CH₂ CH3 have CH₃ CH₂ CH₂ + O₂ flames CH₃ CH₂ CH₂OH Na Bu, H₂SO4 (0) CH₃ CH₂OH Pele Cone. HBR CH₃CH₂ CH₂OH NaOH + OH- CH₂Cl alekoh CH₃ CH₂ CH CH3 a heat Br CH₂C-B + H₂O csta AgNO3 CH₃ CH CH3 + Ag+ OH H₃PO4 heat
II. Draw the structure for the major organic product of each of the following reactions. (7.5 pts each, 45 pts) o 11. Ç(CH3)3 1) CH3CCI, AICI: 2) (CH3)2NH H2, Raney-Ni, heat 12. CO2Me 1) PhMgBr (2 equiv.) 2) H20, H30+ O 13. CNH2 1) Brą, NaOH, H20 o 2) CH3CCI, pyridine 14. HNO3 CHO HOEH НЕОН H OH HO+H CH2OH 4
4. Synthesis Reactions. Draw the feature product of the following reactions. (8 x 3 pts) 1. Mg Ph Br 2. CO2 3. H+ 1. NaOH, ANH, 1. NaOH, CANADA ? 2. Lialla NH2 2. LiAIH4 CH3CH2NH2, NaBH3CN, H+ c. PhD Br (excess) CNH LB (excess) NaOH H+ YO- OH . H' CH3 1. NaOH, H2O NH - 2. H+ 1. NaOH, H2O 2. SOCI . N(CH3)2 HO فه H2NCH3 OCH3
1. Write structures for the lettered organic product(s) in the following reactions: (4 pts each) H, CH2OH A 1) CHCI B 2) OH OH O== + с D + E Conc. KMnO4 OH/H,0 OH PBrz F CH2CH MgBr CH3MgBr H H30 1) 03 2) Zn, H20 2Eq. HBT H3C-CEC-H NaH H3C-C=C-H K
7. Draw the structure of the missing major organic product(s) for each of the following reactions. There is no “No Reaction in any of the answers. Show correct stereochemistry when needed! NO ON Na S204 (excess) NaOH, H20, heat Sebacoyl chloride PhCH OH OH (excess) 0 H2SO4, heat Aryl Bromide 1) Mg, THF 2) CH2=0 3) H20, H307 PhCH,CH,OH1 H2SO4 (catalytie) T heat H2Cro (excess)