Mass of the aluminum cup = 122.0 gm
Temp of Aluminum cup = 18.66 0C
aluminum (specific heat capacity = 0.89 J °C-1 g-1)
Mass of the water = 138.6 gm
Temp of water = 46.57 0C
Water (specific heat capacity = 4.184 J °C-1 g-1)
let the final temp of the system is Tf
So
(mass Al) (Δt Al) (Cp Al) = (mass water) (Δt water) (Cp water)
(122) (Tf-18.66) (0.89) = (138.6) (46.57 -Tf) (4.184)
108.58Tf - 2026.1028 = 27006.054768.- 579.9024Tf
688.7524Tf = 29032.157568
Tf = 42.15 0C
So the final temprature is 42.15 degree celcius
Entropy change is given by
S = mCpLn(T2/T1)
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