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ease be sure that you understand how to handle when there sa tie amongst the hrst atom attachments to the asymmetric center. For instance, the first atoms attached to C1 are C, C, C, and H. Clearly, the His low priority, in a first atom attachment sense, and is given 4.With the three carbon atom tie, we need to consider the second atoms. The carbon to the left of C1 is attached to second atoms: O, O, and O (the double bond implies that carbon is attached to oxygen twice for priority purposes. The carbon to the upper right of C1 is attached to H, and S. The carbon to the lower right of c1 is attached to: H, C, and c The single sulfur trumps any of the other individual second atoms e, not necessarily additive!) and that group is given priority 1 What is the configuration at each of the indicated asymmetric centers in the structure below? O O OH NH H HO NH C2 C1 R C2 R C1 S. C2 R
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