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When performing a calorimetry (for a constant pressure calorimeter) calculation we state that qrxn = -qwater...

When performing a calorimetry (for a constant pressure calorimeter) calculation we state that

qrxn = -qwater

What is the assumption that allows us to use this equation?

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Answer #1

As we know, Calorimeter minimizes the exchange of energy of reation with surrounding.

Because energy can neither be created nor be destroyed during a chemical reaction, there is no overall energy change during the reaction.

Heat produced or consumed in reaction + heat gained or lost by water =must be zero.

Thus qreaction+qwater =0

qreaction =-qwater

This assumption holds if calorimeter does not absorb any heat from surrounding and there is no energy exchange between calorimeter and surrounding.

this is the assumption.

hope u like it.

comment if any issue.

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