Question

For secondary alcohol to a ketone why is the mol ratio important to find out which acid will provide the greatest yield and how does a 1H NMR spectrum help to calculate the mol ratio?

Answer 1

Ans (1) 9 - Because according to le chatesier's Bimciple if the concentration of reactents is increased on the product is removed, then the reaction will occur in the Asword direction. if we be lege amount of reactcort then Product will formed in less amount Generally coil or lilo mole ratto le considered, the best ratio for the maxium vead so of product, nd 1:1 Patio gives only 707 Yield. when we dome oni dallon Ond secondary alcanal , we get more vield oather than primary alcohol, because in case of Secondary duconal, there is no chances to get converted buttainto s t. - COOH group AIJO. r6) Just look at the signals which come out on oneer 14 Ar your desired Aoderce and by- Boduct: nowe check the intensities of both of these so signals. Flora OR: Choose a sienace and calculates the area o h separately of ecoh compound. The 2011. between them is called / known the males patio, Fores! - in the intensity of the signal from 14 of desired Boduct is to and the intensity of oignal from 121 of by Product is 0.2 , then the percentage of byproduct is 2o4., as compared to the desired Product: then the Rarios 100 : 20 desired f0: 2 7 by Product Produce