The reaction 2NO(g)+O2(g)→2NO2(g) is second order in NO and first order in O2. When [NO]= 4.5×10−2 M and [O2]= 3.7×10−2 M , the observed rate of disappearance of NO is 9.9×10−5 M/s . What is the rate of disappearance of O2 at this moment?
The reaction 2NO(g)+O2(g)→2NO2(g) is second order in NO and first order in O2. When [NO]= 4.5×10−2...
The elementary reaction 2NO2 (g) -> 2NO (g) + O2 (g) is second order in NO2 and the rate constant at 660 K is 5.23 M-1s-1. The reaction half-life at this temperature when [NO2]0 = 0.45 M is ____ s.
2NO(g)+O2(g)→2NO2(g) For the above reaction, the following data were collected for the rate of disappearance of NO in the reaction: Experiment [NO] (M) [O2] (M) Initial Rate (M/s) 1 0.0126 0.0125 1.41×10−2 2 0.0252 0.0250 1.13×10−1 3 0.0252 0.0125 5.64×10−2 Part A: What are the units of the rate constant? a) s−1 b) M−1s−1 c) M−2s−1 d) M−3s−1 Part B: What is the rate of disappearance of NO when [NO]=0.0725 and [O2]=0.0100? Express the rate in molarity per second to...
2. (10 pts) Consider the following second-order reaction: 2NO2(g) + 2NO(g)+O2(g) The rate constant is 0.54 M-15-1, at 300 °C. How long would it take for the concentration of NO2 to decrease from 0.62M to 0.28M?
9. The reaction 2NO +O2 → 2NO2 is believed to occur by the following mechanism: 2NO ↔ N2O2 N2O2 + O2 → 2 NO2 a. Assume N2O2 to be in a steady state and derive the rate equation for the overall reaction. b. Under what condition does the rate equation reduce to second order kinetics in NO and first order kinetics in O2 at the same time?
Nitrogen dioxide decomposes to nitric oxide and oxygen via the reaction: 2NO2→2NO+O2 In a particular experiment at 300 ∘C, [NO2] drops from 0.0256 to 0.00889 M in 383 s . The rate of disappearance of NO2 for this period is ________ M/s. 1) 4.36×10−5 2) −9.01×10−5 3) 8.73×10−5 4) 2.29×104 5) 2.18×10−5
Consider the following reaction: 2NO(g)+O2(g)→2NO2(g)2NO(g)+O2(g)→2NO2(g) Estimate ΔG∘for this reaction at each of the following temperatures and predict whether or not the reaction will be spontaneous. (Assume that ΔH∘ΔH∘ and ΔS∘ΔS∘ do not change too much within the give temperature range.) 1) 713 2) 852
The following data were collected for the rate of disappearance ofNO in the reaction 2NO(g) + O2 --> 2NO2(g) : Experiment [NO] (M) [O2] (M) Initial Rate (M/s) 1 0.0126 0.0125 1.41 x 10-2 2 0.0252 0.0125 5.64 x 10-2 3 0.0252 0.0250 1.13 x 10 -1 (a) What is the rate law for the reaciton? (B) What are teh unitsof the rate constant? (c) What is the average value of the rateconstant calculated form teh three data sets? (d)...
Consider the following reaction: 2NO(g)+O2(g)⇌2NO2(g)2NO(g)+O2(g)⇌2NO2(g) The data in the table show the equilibrium constant for this reaction measured at several different temperatures. Temperature K 400 1.9x10^7 425 2.5x10^6 465 1.6x10^5 515 8.8x10^3 600 2.0x10^2 Use the data to find ΔrS∘ΔrS∘ for the reaction. (answer in J K-1 mol-1) The answer is NOT 158
The reaction 2NO2 → 2NO + O2 obeys the rate law: rate = 1.4 x 10-2[NO2]2 at 500 K . What would be the rate constant at 310 K if the activation energy is 80. kJ/mol? This is a second order reaction, giving k the units of M-1S-1 This will not change with the change in temperature. Do not include units in your answer. Exponential numbers need to be entered like this: 2 E-1 means 2 x 10-1. The rate...
2NO2(g) → 2NO(g) + O2(g) Describe the reaction and the importance of the molecules involved. Describe what needs to happen on a molecular level in order for the reaction to take place.