Question
Quantitative analysis help!
Ammoniacal nitrogen can be determined by treatment of the sample with chloroplatinic acid; the product is slightly soluble ammonium chloroplatinate: *8-22. The precipitate decomposes on ignition, yield ing metallic platinum and gaseous products:
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Answer #1

H2PtCl6 + 2 NH4+ -------------> (NH4)2PtCl6 +   2 H+

(NH4)2PtCl6   ---------------> Pt (s) + 2 Cl2 (g) + 2 NH3 (g) + 2 HCl (g)

mass of Pt = 0.5881 g

moles of Pt = 0.5881 / 195.084

                    = 3.0146 x 10^-3 mol

moles of NH3 = 2 x moles of pt

                       = 2 x 3.0146 x 10^-3

                        = 6.029 x 10^-3 mol

mass of NH3 = 6.029 x 10^-3 x 17

                      = 0.1027 g

mass % of NH3 = (0.1027/ 0.2213) x 100

                          = 46.4 %

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