Greater the pKa value , weaker is the acid.
Thus, cycloheptatriene is less acidic than cyclopentadiene
It is so because, cycloheptatriene is aromatically stable and thus doesnot have a tendency to loose proton while cyclopentadiene is a normal alkene which is unsaturated and is in need of the electron.
The pka of cyclopentadiene is found to be 16 while, by contrast, that of cycloheptatriene is...
Why is the pka value of cycloheptatriene so much greater than that of cyclopentadiene? Where pka value of cycloheptatriene =36, Pka value of cyclopentadiene=17
Explain why cyclopentadiene (pKa 16) is many orders of
magnitude more acidic than cyclopentane (pKa > 50). (Hint: Draw
the structural formula for the anion formed by removing one of the
protons on the −CH2− group, and then apply the Hückel criteria for
aromaticity.)
Explain why cyclopentadiene (PK, 16) is many orders of magnitude more acidic than cyclopentane (pka > 50). (Hint: Draw the structural formula for the anion formed by removing one of the protons on the -CH2- group,...
CHM 250 for 10 c)Cyclopentadiene is much more acidic than cycloheptatriene. (Ka cyclopentadiene, Ka 103% for cycloheptatriene.) explain why? H 3 points H H H H H H H H H H H T T 2) Draw the Molecular Orbital diagrams (Frost circle) of Benzene and cyclobutadiene in the ground state. Specify whether the molecule is aromatic/antiaromatic a) Benzene aromatic/antiaromatic (4+1) aromatic/antiaromatic (4+1) b) Cyclobutadiene 13 (2 1. O3 2. Zn/H20 -Эн -Эн H I A) I and II B)...
For each of the acid-base reactions in Section, compare the pKa values of the acids on either side of the equilibrium arrows and convince yourself that the position of equilibrium is in the direction indicated. (The pka values you need can be found in Section 2.3 or in Problem.) Problem: a. Which is a stronger base, CH3COO-or HCOO-? (The pKa of CH3COOH is 4.8; the p£a of HCOOH is 3.8.) b. Which is a stronger base, HO- or-NH2? (The pka...
Due to the interactions with other
amino acids in the protein, the pKa of Glu35 and Asp 52
are both shifted from the standard values found in our
table. The actual pKa values are 5.9 for
Glu35 and 4.5 for Asp52 respectively. Using these pKa values, and
the H-H equation, calculate the ratio of deprotonated to protonated
side chains for both Glu35 and Asp59 at pH 4.0, pH 5.2 and pH 6.0
(six total calculations). Using your
calculations, clearly explain why the...
6. Usina resonance structures, explain why acetaldenyde has a pka of 17, while acetone of 19. 7. Using resonance structures, explain why methyl acetate (pka 25) is less acidic than acetone (pka 19). 8. Rank the following in order from least to most acidic. Explain your ranking, using resonance structures with your explanation. & la
Our instructor said that if the pKa is >16 a reagent should
completely deprotonate an alkylthiol. But he also said the pKa
difference has to be at least 5, preferably 10, to completely
deprotonate.
I'm not sure what pKa to use for some of these since they're
sodium based-NaCN in particular. (And the pKa for a generic
alkylthiol.
I think these are right:
H20=15.8 so no.
NH3=38 so yes
NaNH2=38 so yes
NaO2CCH3=24 so yes (?) its the conjugate base...
5. The alcohol CH CH SH has an unusually small pka of approximately 9.4 relative to ethanol, CH CH OH (pka - 16). a. Is CH,CH,SH more or less acidic than ethanol? (2 pts) b. Draw the conjugate base for each and explain the difference in acidity between CH, CH SH and CH CH2OH by analyzing the structures of the conjugate bases. (4 pts) c. Provide an arrow-pushing scheme for the reaction of one mole of CH,CH,SH with one mole...
what is the pKa?
H -10 -6 -4 -2 0 3-5 5-7 9-11 12. 15-16 18 25 30 36-40 41 44 50
Chapter 16 Relating pKa and pKb Review I Constants | Periodic Table Ar Learning Goal: To understand the relation between the strength of an acid or a base and its pKa and pKb values. The degree to which a weak acid dissociates in solution is given by its acid-ionization constant, Ka. For the generic weak acid, HA, HA(aq) A (aq) H (aq) and the acid-ionization constant is given by a HA Similarly, the degree to which a weak base reacts...