Question

The pka of cyclopentadiene is found to be 16 while
0 0
Add a comment Improve this question Transcribed image text
Answer #1

Greater the pKa value , weaker is the acid.

Thus, cycloheptatriene is less acidic than cyclopentadiene

It is so because, cycloheptatriene is aromatically stable and thus doesnot have a tendency to loose proton while cyclopentadiene is a normal alkene which is unsaturated and is in need of the electron.

Add a comment
Know the answer?
Add Answer to:
The pka of cyclopentadiene is found to be 16 while, by contrast, that of cycloheptatriene is...
Your Answer:

Post as a guest

Your Name:

What's your source?

Earn Coins

Coins can be redeemed for fabulous gifts.

Not the answer you're looking for? Ask your own homework help question. Our experts will answer your question WITHIN MINUTES for Free.
Similar Homework Help Questions
  • Why is the pka value of cycloheptatriene so much greater than that of cyclopentadiene? Where pka...

    Why is the pka value of cycloheptatriene so much greater than that of cyclopentadiene? Where pka value of cycloheptatriene =36, Pka value of cyclopentadiene=17

  • Explain why cyclopentadiene (pKa 16) is many orders of magnitude more acidic than cyclopentane (pKa >...

    Explain why cyclopentadiene (pKa 16) is many orders of magnitude more acidic than cyclopentane (pKa > 50). (Hint: Draw the structural formula for the anion formed by removing one of the protons on the −CH2− group, and then apply the Hückel criteria for aromaticity.) Explain why cyclopentadiene (PK, 16) is many orders of magnitude more acidic than cyclopentane (pka > 50). (Hint: Draw the structural formula for the anion formed by removing one of the protons on the -CH2- group,...

  • CHM 250 for 10 c)Cyclopentadiene is much more acidic than cycloheptatriene. (Ka cyclopentadiene, Ka 103% for...

    CHM 250 for 10 c)Cyclopentadiene is much more acidic than cycloheptatriene. (Ka cyclopentadiene, Ka 103% for cycloheptatriene.) explain why? H 3 points H H H H H H H H H H H T T 2) Draw the Molecular Orbital diagrams (Frost circle) of Benzene and cyclobutadiene in the ground state. Specify whether the molecule is aromatic/antiaromatic a) Benzene aromatic/antiaromatic (4+1) aromatic/antiaromatic (4+1) b) Cyclobutadiene 13 (2 1. O3 2. Zn/H20 -Эн -Эн H I A) I and II B)...

  • For each of the acid-base reactions in Section, compare the pKa values of the acids on...

    For each of the acid-base reactions in Section, compare the pKa values of the acids on either side of the equilibrium arrows and convince yourself that the position of equilibrium is in the direction indicated. (The pka values you need can be found in Section 2.3 or in Problem.) Problem: a. Which is a stronger base, CH3COO-or HCOO-? (The pKa of CH3COOH is 4.8; the p£a of HCOOH is 3.8.) b. Which is a stronger base, HO- or-NH2? (The pka...

  • Due to the interactions with other amino acids in the protein, the pKa of Glu35 and...

    Due to the interactions with other amino acids in the protein, the pKa of Glu35 and Asp 52 are both shifted from the standard values found in our table.  The actual pKa values are 5.9 for Glu35 and 4.5 for Asp52 respectively. Using these pKa values, and the H-H equation, calculate the ratio of deprotonated to protonated side chains for both Glu35 and Asp59 at pH 4.0, pH 5.2 and pH 6.0 (six total calculations).  Using your calculations, clearly explain why the...

  • 6. Usina resonance structures, explain why acetaldenyde has a pka of 17, while acetone of 19. 7. Using resonance st...

    6. Usina resonance structures, explain why acetaldenyde has a pka of 17, while acetone of 19. 7. Using resonance structures, explain why methyl acetate (pka 25) is less acidic than acetone (pka 19). 8. Rank the following in order from least to most acidic. Explain your ranking, using resonance structures with your explanation. & la

  • Our instructor said that if the pKa is >16 a reagent should completely deprotonate an alkylthiol....

    Our instructor said that if the pKa is >16 a reagent should completely deprotonate an alkylthiol. But he also said the pKa difference has to be at least 5, preferably 10, to completely deprotonate. I'm not sure what pKa to use for some of these since they're sodium based-NaCN in particular. (And the pKa for a generic alkylthiol. I think these are right: H20=15.8 so no. NH3=38 so yes NaNH2=38 so yes NaO2CCH3=24 so yes (?) its the conjugate base...

  • 5. The alcohol CH CH SH has an unusually small pka of approximately 9.4 relative to ethanol, CH CH OH (pka - 16). a...

    5. The alcohol CH CH SH has an unusually small pka of approximately 9.4 relative to ethanol, CH CH OH (pka - 16). a. Is CH,CH,SH more or less acidic than ethanol? (2 pts) b. Draw the conjugate base for each and explain the difference in acidity between CH, CH SH and CH CH2OH by analyzing the structures of the conjugate bases. (4 pts) c. Provide an arrow-pushing scheme for the reaction of one mole of CH,CH,SH with one mole...

  • what is the pKa? H -10 -6 -4 -2 0 3-5 5-7 9-11 12. 15-16 18...

    what is the pKa? H -10 -6 -4 -2 0 3-5 5-7 9-11 12. 15-16 18 25 30 36-40 41 44 50

  • Chapter 16 Relating pKa and pKb Review I Constants | Periodic Table Ar Learning Goal: To understa...

    Chapter 16 Relating pKa and pKb Review I Constants | Periodic Table Ar Learning Goal: To understand the relation between the strength of an acid or a base and its pKa and pKb values. The degree to which a weak acid dissociates in solution is given by its acid-ionization constant, Ka. For the generic weak acid, HA, HA(aq) A (aq) H (aq) and the acid-ionization constant is given by a HA Similarly, the degree to which a weak base reacts...

ADVERTISEMENT
Free Homework Help App
Download From Google Play
Scan Your Homework
to Get Instant Free Answers
Need Online Homework Help?
Ask a Question
Get Answers For Free
Most questions answered within 3 hours.
ADVERTISEMENT
ADVERTISEMENT