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compare and explain the attraction between Fe 2+ and cellulose , Cu 2+ and cellulose ,...

compare and explain the attraction between Fe 2+ and cellulose , Cu 2+ and cellulose , and Ni 2+ and cellulose. ( This is relating to paper chromotohrapy, the solvent used is HCL)

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Answer #1

Attraction of different metal ion with cellulose in Paper chromatography

CONCEPT

Different metal ion flow on cellulose paper with different rate or we can say different metal ion react with cellulose paper is different ,which show as Rf value

retension factor or Rf value is equal to distance travel by solute(metal ion )divided by distance travel by solvent, which is different for all metal ion(generally )

Ni 2+ =0.09 dark violet spot and Cu2+ =0.60 white spot , means nickel move less on celluolse paper ( which show more attractio with celluolse paper) and copper move rapidly on cellulose paper (less attraction with cellulose paper) respectively

HCL help into stop multiple spot

PROCEDURE

Cellulose act as a stationary phase ,which is dipped into solvent (normally Acetone +HCL+H2O) in a glass jar.

A Spot of mixture was put on cellulose paper ( 1 or 2 cm above solvent ),then mixture was leave for sometime.(30 to 45 mintute) to move solute on cellulose paper Then Rf value calculated my measuring distance travel by solute and solvent  

Cmpd 1 Cmpd 1 2F1 origin ....J.J.-.. origin Good Separation - Well Resolved Poor Separation - Not Resolved

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