a) Predict the solubility of glycerol, a trihydroxyl alcohol, with the formula C3H5(OH)3 in H2O and in a hydrocarbon solvent.
b) Do the same for the alcohol C16H33OH
a) Glycerol has three hydroxyl (OH) groups which makes the compound polar and gives rise to similar properties as that of water. It can easily make hydrogen bonding with water molecules. This increases solubility of glycerol in water. But in hydrocarbons, it is insoluble. The increased polar character makes it insoluble in hydrocarbon solvent.
b) Alcohol C16H33OH is a higher alcohol which contains a long chain of 16 carbons. Lower alcohols are soluble in water because of the presence of OH group. But as we move to higher alcohols, the solubility decreases in water. The long chain makes the compound non-polar and thus makes t water repellant. So, this alcohol is insoluble in water. But as it becomes non polar, so it is soluble in hydrocarbon solvent.
a) Predict the solubility of glycerol, a trihydroxyl alcohol, with the formula C3H5(OH)3 in H2O and...
A solution of glycerol,C3H5(OH)3 , in 645 g of water has a boiling point of 102.9 °C at a pressure of 760 mm Hg. What is the mass of glycerol in the solution? What is the mole fraction of the solute? ( K bp for H2O is 0.5121 C/m.) Mass: ___ g Mole Fraction: ____
Name Structure 1) ethanol (ethyl alcohol) State (s), (0) H2O Notes CH-CH2-OH Sol., Insol CH4 Sol., Insol. IS Is I No change 2) t-butyl alcohol (2-methyl-2- propanol) CH CH3-C-CH3 1 Is Is I No change OH 3) n-hexyl alcohol (1-hexanol) CH3CH,CH,CH,CHCH2-OH 4) dodecanol 5) 1,6-hexanediol CH CH CH CH CHCH OH ОН 6) decanoic acid Part A) save sample for part B OHS Insols decanoic acid Part B) changed to sodium decanoate after rxn with NaOH After adding the NaOH...
Condensed formula Functional group Water Ether solublesoluble Compound name Pentane Diethyl ether Isopropyl alcohol Propylene glycol Glycerol Rank the alcohols in order of increasing viscosity. least most Explain the solubility of isopropyl alcohol in each solvent.
Predict the products of the following reactions.
H2O + H2O- OH + H2O R, & H2O - - R-NOL + H2O. hook + H2O - kort H2o
1.How many grams of glucose (C6H12O6) are produced if 17.3 mol of H2O are reacted according to this balanced chemical equation? 6CO2 + 6H2O → C6H12O6 + 6O2 2. Nitroglycerin [C3H5(ONO2)3] is made by reacting nitric acid (HNO3) with glycerol [C3H5(OH)3] according to this reaction: C3H5(OH)3 + 3HNO3 → C3H5(ONO2)3 + 3H2O If 87.4 g of HNO3 is reacted with excess glycerol, what mass of nitroglycerin can be made? 3. Precipitation reactions, in which a solid (called a precipitate) is...
19. Predict how the following will affect the solubility of Al(OH)s a. In solution of 0.1 MA b. pH of 4.0 c. pOH of 4.0-Al(OH)s is amphoteric-Al(OH)s (aq) + OH, (aq)-→ [Al(OH) (aq) 20. Predict how the following will affect the solubility of AgBr a. Addition of Na S2Os complex forms in Ag' (a) 2S20 (aq) [Ag(S 0s)2l (aq) 21. Calculate the molar solubility for the following solutions of LiF (Ksp 3.8 103) a. In 0.1 M NaF . In...
AUS. I 3. Compare glycerol with ethanol. a. They both contain 3 carbons in the skeleton. b. They both have the hydroxy on an interior carbon. Glycerol is a long chain alcohol; ethanol is a short chain alcohol. d. Glycerol is a triol; ethanol is not a triol. Ans: C 4. What is the correct IUPAC name for the following compound? CH3CH2CHCH2 CH3 CH2 он a. 3-methylpentanol b. 2-ethyl-1-butanol C. 2-ethylbutanol d. 1-ethyl-2-butanol Ans: 5. What is the correct IUPAC...
Predict the effect on the molar solubility of Mg(OH)2 (higher, lower, no change) with an explanation: a.) Mg(OH)2 was dissolved in a solution of 0.1 M HCl HCl --> H3O+ + Cl- Mg(OH)2 --> Mg2+ + 2OH-
Liquid nitroglycerin, a very powerful explosive, has the formula C3H5(NO3)3. It is unstable and decomposes to form carbon dioxide, nitrogen, water, and oxygen. a. Write the balanced chemical equation for this decomposition. Write the starting materials on the left and the products on the right side of the arrow. HINT: Don’t forget the diatomic molecules! b. How many grams of carbon dioxide are formed from 10.00 grams of liquid nitroglycerin? Use significant figures and show your work.
Predict the product from the following sequence: H OH H07 NaBH CH;OH ? heat (-H2O) OH OH Z and E) H ОН ОН II DI (Z and E) OH H H OH IV O A. IV OB. OC. V OD. 11 E. III