Answer 4- blank reagent means a solution having all component as sample solution except the analyte to be determined. The compounds in the solution may have the impurity of the analyte to be determined and may absorb the radiation of same wavelength. Most of time blank reagent is used to caliberate the instrument to ensure that the measurement device gives a zero signal when there is no sample present so signal of blank can be substracted to get the signal of desired analyte
Answer 5- Fe2+ + 2H2O = Fe(OH)2 + H+ This reaction would be a problem in determination of Iron because of the absence of charge transfer specially Ligand metal charge transfer as in case of iron-phenanthroline complex. Due to absence of charge transfer and d-d transfer Fe(OH)2 is colourless and can not be determined under photospectroscopy technique and exact amount of Fe can not be determined. This can be prevented by maintaining a pH of 2-3. According to le chatelier principle more H+ concentration shifts this reaction towards back.
Can you answer question 4 & 5? The experiment and porcedure is posted below Question 4...
What is the purpose of the acid added in the beginning of the experiment? CHM3120C Analytical Chemistry Lab Lab 7. Spectrophotometric Determination of Iron in Mole's Salt with e-Phenanthroline Required Reagents and Supplies 50 mL of 0.0005 -0.0006 M of Moher's solution unknown. 10 of Hydroxylamine hydrochloride (NH2OH, HCT, 500 ml of phenantholine solution contains 05 of-phenanthroine monohydrate). 83 g of sodium acetate (NOAC3H20) in 500 ml of water (for 1.2 M of phl 5 buffer som minimum 3 of...
THE DETERMINATION OF IRON BY SPECTROPHOTOMETRY INTRODUCTION In this experiment, the red-orange colored complex formed between iron(II) and 1,10- phenanthroline (Eqn.) is used in determination of iron by spectrophotometry. Fe+3PhenH Fe(Phen)2 +3H red-orange (A 512 nm) An excess of reducing reagent, such as hydroxylamine or hydroquinone, is often used to reduce and maintain iron in +2 oxidation state. The complex, once formed, is very stable, and can be stored for a long time. Required Reading: Skoog and West (9E): Chapter...
Question 1 2 pts 3.34 mL of an unknown glucose solution was diluted in a 100.00 mL of volumetric flask with distilled water. 10mL of that solution and 4.00 mL of the ferricyanide reagent was placed in a second 100.00 mL volumetric flask and diluted to the mark with distilled water. Spectrophotometric analysis of the glucose/ferricyanide solution showed that the concentration of glucose was 0.070 M. What is the concentration of glucose in the unknown solution?
Question 1 2 pts 3.34 mL of an unknown glucose solution was diluted in a 100.00 mL of volumetric flask with distilled water. 10mL of that solution and 4.00 mL of the ferricyanide reagent was placed in a second 100.00 mL volumetric flask and diluted to the mark with distilled water. Spectrophotometric analysis of the glucose/ferricyanide solution showed that the concentration of glucose was 0.070 M. What is the concentration of glucose in the unknown solution?
A student weighs out 14.6 g of AlBrz, transfers it to a 300 mL volumetric flask, adds enough water to dissolve the solid and then adds water to the 300 mL mark on the neck of the flask. Calculate the concentration (in molarity units) of aluminum bromide in the resulting solution? Calculate the mass, in grams of sodium iodide that must be added to a 250 mL volumetric flask in order to prepare 250 mL of a 0.138 M aqueous...
A standard solution of iron was made by weighing 0.075 g of Fe(NH4)2(SO4)2 6(H2O) in 250 mL. Aliquots of this standard solution (see below) were transferred to a 100 mL volumetric flask, pH adjusted with citrate, and reacted with hydroquinone and o-phenanthroline and diluted to volume (100 mL). The absorbance was measured in a 1.0-cm cell using a Genesys 20 Spectrophotometer at 508 nm: Aliquot of standard solution Absorbance 1.0 mL 0.079 2.0 mL 0.163 5.0 mL 0.413 10.0 mL...
In the laboratory, a student adds 19.3 g of potassium acetate to a 125 mL volumetric flask and adds water to the mark on the neck of the flask. Calculate the concentration in mol/L) of potassium acetate, the potassium ion and the acetate ion in the solution [KCH3COO) - [K] [CH3C00] = 1 A student wishes to prepare 300-ml of a 0.236 M iron(III) acetate solution using solid iron(III) acetate, a 300-ml volumetric flask, and deionized water (a) How many...
Please answer within 40 minutes for when the question is due, thank you! |-/0.5 points GVSUCHEM116V2 14.6.3.P004. My Notes Calculating the pH of a Buffer Solution To prepare a buffer you weigh out 9.00 grams of KNO2 and place it into a 500.00 mL volumetric flask. To this flask you add 18.0 mL of 3.80 M HNO, and then fill it about halfway with distilled water, swirling to dissolve the contents. Finally, the flask is filled the rest of the...
In the laboratory you dissolve 23.7 g of iron(II) acetate in a volumetric flask and add water to a total volume of 375 mL. What is the molarity of the solution? M. What is the concentration of the iron(II) cation? M. What is the concentration of the acetate anion? M.
2. (a) What is the formula and color of the complex that forms when Fe" reacts with 1,10- phenanthroline? (b) This complex absorbs strongly at which wavelength (in nm) of visible light? Indicate the color of light having this wavelength. (c) Is the color of the complex the same as th color of the light of maximum absorption? Would you expect them to be the same? Explain 3. What is the molar mass (in g/mol) of Fe(NH)(SO4): 6 H,0? 4....