1.ANSWER:
To avoid oxygen toxicity and nitrogen narcosis, deep-sea divers breathe a specialized mixture of gas that is Heliox which is a mixture of helium and oxygen. Mainly nitrox is used by a diver but it is not useful in deep-sea.
Hence, the fourth option is correct.
2.ANSWER:
Here,
Number of moles of NH3 = (PV)/(RT)
= (1.5 atm x 12.5 L)/(0.082057 L atm mol-1K-1 x 298 K)
= 0.767 moles
Number of moles of O2 = (PV)/(RT)
= (1.1 atm x 18.9 L)/(0.082057 L atm mol-1K-1 x 323 K)
= 0.784 moles
In reaction we can see that 4 moles of NH3 gives 6 moles of water
So, 1 moles of NH3 gives = 1.5 moles of water
and, 0.767 moles of NH3 gives = (1.5 x 0.767) moles of water
= 1.1505 moles of water.
Now,
The mass of water = number of moles x molar mass
= 1.1505 mol x 18.01528 g/mol
= 20.7 g H2O
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