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The zeolite ZSM-5 is a very important catalyst in industry and is famous for shape-selective catalysis....

The zeolite ZSM-5 is a very important catalyst in industry and is famous for shape-selective catalysis. Please write down the representative shape-selective reaction of converting toluene into xylene, and briefly explain the high shape-selectivity of the products?

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Answer #1

The representative shape selective reaction is shown below.

ZSM-5 CH₂OH

ZSM-5 can selectively convert toluene to xylene. Among the three xylene, para substituted xylene has the highest diffusivity through ZSM-5. The shape of the pores of ZSM-5 is suitable for accommodation of para xylene. Therefore after converting to para xylene, it diffuses out of the catalyst quickly and the conversion takes place smoothly.

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