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Determine the bond order for F2, F2+ and F2-. Which molecule should be the most stable?

Determine the bond order for F2, F2+ and F2-. Which molecule should be the most stable?
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Answer #1
Concepts and reason

The concept used to solve bond order and stability of molecules is a molecular orbital theory. Firstly the molecular orbital diagram is drawn than bond order is calculated using the bonding and antibonding orbitals.

Fundamentals

Bond Order:

It tells the number of chemical bonds between the atoms.

The bond order can be calculated by using the formula given below.

Bond order = !
- [N
-N. ]
……(1)

Here, is a number of electrons in bonding molecular orbital and number of electrons in an antibonding molecular orbital.

The molecular mass of is . The molecular orbital configuration of of increasing order of energy is shown below.

ols,ols,c2s’,o*2s°,02p, ?, 12p, = n2p,, n° 2p, = 2p,?

molecular orbital diagram of F2
LUMO
0*2px
HOMO
/
4 |
HOMO
***2py T*2pz
2P
Te
17t2p
PPY PL
Iz
T2py
02px
0*2s
2s
o2s
0*1s
ols

To calculate the bond order of substitute the value of as and as in the equation (1).

Bond order = [
[10 -8 ]
Bond order = 1

To calculate the bond order of substitute the value of as and as in the equation (1).

Bond order = [10 - 7]
Bond order = 1.5

To calculate the bond order of substitute the value of as and as in the equation (1).

Bond order = [10-91
Bond order = 0.5

The bond order of is , which is the highest among all others.The most stable molecule is .

Ans:

The bond order of is .

The bond order of is .

The bond order of is .

The most stable molecule is .

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