Homework Answers
The first reaction is the Bromination reaction in the Bromine molecule is created and which is substituted by the electrophilic aromatic substitution mechanism,
The second reaction is an example of the Diel's- alder reaction, with first the elimination of the sulphur dioxide and the [4+2] cycloaddition happens.
![131 NH Nabr, Nacho Br - AwH, Eton 2 NaBr + +2lho Naelo +2H aelo Br. + Nael + 2 Naoh. Bromination mention + so, [4+2] Cyel a](http://img.homeworklib.com/questions/9f179860-f86b-11eb-832e-ef40f3040745.png?x-oss-process=image/resize,w_560)
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2. (8 pts) Draw the major product(s) of the given reactions. For each, briefly justify why...
1. Draw the major product formed from the following elimination reactions. (4 pts) NaOET EtOH, heat...
1. Draw the major product formed from the following elimination reactions. (4 pts) NaOET EtOH, heat 85% H3PO4 १ 80°C heat Y Br + BOKBLOH host + t-BUOKA-BOH EtOH TH + Naget 55°C
" LU PUMPS 1. Draw the major product formed from the following elimination reactions. (4 pts)...
" LU PUMPS 1. Draw the major product formed from the following elimination reactions. (4 pts) NaOEt EtOH, heat 85% H3PO4 80° C heat Y + t-BuOKA-BOH EtOH + NaOEt 55°C - Complete the following reactions with correct stereochemistry (4 points) 1. Sia BH 1. =co Na 2 H₂Oh 2. H2O2, NaOH Na NH3 mCPBA Line- correct stereochemistry correct stereochemistry
11. (24 pts.] Draw the major product/s of each of the following reactions. H2SO4 0.- at...
11. (24 pts.] Draw the major product/s of each of the following reactions. H2SO4 0.- at +3 - +3 ono.grous e in 1. TSCI 2. NaCN
Draw the major expected organic product(s) for each of the following reactions. Be sure to indicate...
Draw the major expected organic product(s) for each of the
following reactions. Be sure to indicate stereochemistry when
needed.
OH 1) TsCl, pyr 2) NaBr Br HS Give neutral product. بیاہ 1) SOCl2, pyridine 2) NaSH OH Br DBU d 1) PBr 3 2) KOt-Bu OH
3. Give the major organic product(s) of each of the following reactions or sequences of reactions....
3. Give the major organic product(s) of each of the following reactions or sequences of reactions. Br2 CH3COOH OH 1. Bry, PB 2. H2O CH, III 13, NaOH (excess) HC-C-C- CH H20 CH; 1.2 equiv. NaOet, EtOH VOE2.AAB O= OE: + (CH),CHCHCH,Br 1. NOE! EtOH 2.H20, heat
13. (8 pts) Draw the major product(s) for reactions through F in the spaces provided. 1....
13. (8 pts) Draw the major product(s) for reactions through F in the spaces provided. 1. Nah 1 Nal NaBH D 2. CH,CH,Bro CH,CH,OH CHCE 2 CH,CH,Br
5. a) Draw the major 1,2-addition product and the major 1,4-addition product of each of the...
5. a) Draw the major 1,2-addition product and the major 1,4-addition product of each of the following reactions. Label each product as either the 1,2-addition product or 1,4-addition product and as either the thermodynamic or kinetic product. (12 pts) H" catalyst H catalyst b) Consider the reaction of a nucleophile with conjugated carbonyl. Provide an example of a nucleophile that would favor the 1,2-addition product and explain why. Provide an example of a nucleophile that would favor the 1,4-addition product...
3. Predict the major product(s) for each of the following reactions: (18 pts) Heat Heat Heat...
3. Predict the major product(s) for each of the following reactions: (18 pts) Heat Heat Heat diversos Heat OHC Heat o Heat
II. Draw the structure for the major organic product of each of the following reactions. (7.5...
II. Draw the structure for the major organic product of each of the following reactions. (7.5 pts each, 45 pts) 11. Ç(CH3)3 o 1) CH3CCI, AICI 2) (CH3)2NH H2, Raney-Ni, heat
2. (4 pts each) In the box provided, draw the product(s) of the reactions given. Remember...
2. (4 pts each) In the box provided, draw the product(s) of the reactions given. Remember to include stereochemistry if necessary. If you create a racemic mixture, draw BOTH enantiomers and write "Racemic" A) CI S-CH3 он Pyridine B) он H2SO4 C) он H2CrO4 D) PCC он E) HBr он 2of 4
1. Draw the major product formed from the following elimination reactions. (4 pts) NaOET EtOH, heat 85% H3PO4 १ 80°C heat Y Br + BOKBLOH host + t-BUOKA-BOH EtOH TH + Naget 55°C
" LU PUMPS 1. Draw the major product formed from the following elimination reactions. (4 pts) NaOEt EtOH, heat 85% H3PO4 80° C heat Y + t-BuOKA-BOH EtOH + NaOEt 55°C - Complete the following reactions with correct stereochemistry (4 points) 1. Sia BH 1. =co Na 2 H₂Oh 2. H2O2, NaOH Na NH3 mCPBA Line- correct stereochemistry correct stereochemistry
11. (24 pts.] Draw the major product/s of each of the following reactions. H2SO4 0.- at +3 - +3 ono.grous e in 1. TSCI 2. NaCN
Draw the major expected organic product(s) for each of the
following reactions. Be sure to indicate stereochemistry when
needed.
OH 1) TsCl, pyr 2) NaBr Br HS Give neutral product. بیاہ 1) SOCl2, pyridine 2) NaSH OH Br DBU d 1) PBr 3 2) KOt-Bu OH
3. Give the major organic product(s) of each of the following reactions or sequences of reactions. Br2 CH3COOH OH 1. Bry, PB 2. H2O CH, III 13, NaOH (excess) HC-C-C- CH H20 CH; 1.2 equiv. NaOet, EtOH VOE2.AAB O= OE: + (CH),CHCHCH,Br 1. NOE! EtOH 2.H20, heat
13. (8 pts) Draw the major product(s) for reactions through F in the spaces provided. 1. Nah 1 Nal NaBH D 2. CH,CH,Bro CH,CH,OH CHCE 2 CH,CH,Br
5. a) Draw the major 1,2-addition product and the major 1,4-addition product of each of the following reactions. Label each product as either the 1,2-addition product or 1,4-addition product and as either the thermodynamic or kinetic product. (12 pts) H" catalyst H catalyst b) Consider the reaction of a nucleophile with conjugated carbonyl. Provide an example of a nucleophile that would favor the 1,2-addition product and explain why. Provide an example of a nucleophile that would favor the 1,4-addition product...
3. Predict the major product(s) for each of the following reactions: (18 pts) Heat Heat Heat diversos Heat OHC Heat o Heat
II. Draw the structure for the major organic product of each of the following reactions. (7.5 pts each, 45 pts) 11. Ç(CH3)3 o 1) CH3CCI, AICI 2) (CH3)2NH H2, Raney-Ni, heat
2. (4 pts each) In the box provided, draw the product(s) of the reactions given. Remember to include stereochemistry if necessary. If you create a racemic mixture, draw BOTH enantiomers and write "Racemic" A) CI S-CH3 он Pyridine B) он H2SO4 C) он H2CrO4 D) PCC он E) HBr он 2of 4
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