2 faraday of electricity will liberate 0.5 moles of oxygen.
1 faraday of electricity will liberate 0.5 /2 = 0.25 moles of oxygen.
0.25 moles of oxygen = 0.25 * 32 = 8g of O2
4. In the electrolysis of acidified water, the anodic reaction is: H2O(l) + 1/202(g) + 2H+(aq)...
When a carbonate solution is acidified, carbon dioxide is produced. 2H+(aq) + CO32-(aq) → H2O(l) + CO2(g) (a) Can we say anything about the sign of the entropy change without doing any calculations? (b) Calculate the entropy change for this reaction. please use the commonly found entropy values found online for each molecule.
Classify the half‑reactions as reduction half‑reactions or oxidation half‑reactions. H2(g)⟶2H+(aq)+2e−H2(g)⟶2H+(aq)+2e− 12O2(g)+2H+(aq)+2e−⟶H2O(g)12O2(g)+2H+(aq)+2e−⟶H2O(g) Cd(s)+2OH−(aq)⟶Cd(OH)2(s)+2e−Cd(s)+2OH−(aq)⟶Cd(OH)2(s)+2e− 2NiO(OH)(s)+2H2O(l)+2e−⟶2Ni(OH)2(s)+2OH−(aq)2NiO(OH)(s)+2H2O(l)+2e−⟶2Ni(OH)2(s)+2OH−(aq) Fe(s)⟶Fe2+(aq)+2e−Fe(s)⟶Fe2+(aq)+2e− oxidation reduction reduction oxidation reduction
The enzyme carbonic anhydrase catalyzes the reaction CO2(g)+H2O(l)−→−HCO3−(aq)+H+(aq).CO2(g)+H2O(l)→ HCO3−(aq)+H+(aq). In water, without the enzyme, the reaction proceeds with a rate constant of 0.039s−10.039 s−1 at 25°C.25 °C. In the presence of the enzyme in water, the reaction proceeds with a rate constant of 1.0×106s−11.0×106 s−1 at 25°C.25 °C. Assuming the collision factor is the same for both situations, calculate the difference in activation energies for the uncatalyzed versus enzyme- catalyzed reaction.
Given the following reduction half-reactions: Fe3+(aq)+e−→Fe2+(aq) E∘red=+0.77V S2O2−6(aq)+4H+(aq)+2e−→2H2SO3(aq) E∘red=+0.60V N2O(g)+2H+(aq)+2e−→N2(g)+H2O(l) E∘red=−1.77V VO+2(aq)+2H+(aq)+e−→VO2+(aq)+H2O(l) E∘red=+1.00V Part A Write balanced chemical equation for the oxidation of Fe2+(aq) by S2O2−6 (aq). Calculate the equilibrium constant K for this reaction at 298 K. Part B Write balanced chemical equation for the oxidation of Fe2+(aq) by N2O(g). Part C Write balanced chemical equation for the oxidation of Fe2+(aq) by VO+2(aq). Calculate the equilibrium constant K for this reaction at 298 K.
Given the following reduction half-reactions: Fe3+(aq)+e−→Fe2+(aq) E∘red=+0.77V S2O2−6(aq)+4H+(aq)+2e−→2H2SO3(aq) E∘red=+0.60V N2O(g)+2H+(aq)+2e−→N2(g)+H2O(l) E∘red=−1.77V VO+2(aq)+2H+(aq)+e−→VO2+(aq)+H2O(l) E∘red=+1.00V Write balanced chemical equation for the oxidation of Fe2+(aq) by S2O2−6(aq). Calculate ΔG∘ for this reaction at 298 K. Calculate the equilibrium constant Kfor this reaction at 298 K. Write balanced chemical equation for the oxidation of Fe2+(aq) by N2O(g). Calculate ΔG∘ for this reaction at 298 K. Calculate the equilibrium constant Kfor this reaction at 298 K. Write balanced chemical equation for the oxidation of Fe2+(aq)...
2CrO4 2-(aq) + 2H+ (aq) ⇌ Cr2O7 2-(aq) + H2O(l) reaction mechanism CrO3 intermediate
Consider the following unbalanced reaction: 1035(aq) + (aq) + H+(aq) → 12(s) + H2O(1) The correctly balanced reduction half-reaction is: (A) 21+(aq) → 12(s) + 2e- (B) 2H+(aq) + 2e → H2O(1) (C) 103 (aq) + (aq) → 12(s) + 302-(aq) + 4e (D) 2103(aq) + 12H+(aq) + 10 → 12(s) + 6H2O(1) (E) 61-(aq) + 8H+(aq) + 2e → 312(s) + 4H2O(1)
Refer to the following standard reduction half-cell potentials at 25∘C : VO2+(aq)+Ni2+(aq)2H+(aq)++2e−e−→ →Ni(s)VO2+(aq) +H2O(l)E∘=−0.23V E∘=0.99V Part A Part complete An electrochemical cell is based on these two half-reactions: Oxidation:Reduction:Ni(s)VO2+(aq,0.017M)+2H+(aq,1.3M)+e−→→Ni2+(aq,2.5M)+2e−VO2+(aq,2.5M)+H2O(l) Calculate the cell potential under these nonstandard concentrations.
26. Hydrogen peroxide decomposes into water and oxygen in a first-order process. H2O2(aq) → H2O(l) + 1/2 O2(g) 26. Hydrogen peroxide decomposes into water and oxygen in a first-order process. H2O2(aq) → H2O(2) + 1/2O2(g) At 20.0 °C, the half-life for the reaction is 3.05 x 104 seconds. If the initial concentration of hydrogen peroxide is 0.52 M, what is the concentration after 8.00 days?
Sodium hydroxide can be produced by electrolysis of NaCl solution 2NaCl(aq) + 2 H2O(l) à 2 NaOH(aq) + H2(g) + Cl2(g) A 100 g of 20 % aqueous solution of NaClwas used and conversion of NaCl is 90 %. Neglecting solubility of H2 and Cl2 in water, calculate % NaOH in the aqueous product. Use molecular balance method.