Question

In a basic aqueous solution, chloromethane undergoes a substitution reaction in which Cl− is replaced by...

In a basic aqueous solution, chloromethane undergoes a substitution reaction in which Cl− is replaced by OH−:
CH3Cl(aq)+OH−(aq)⇌CH3OH(aq)+Cl−(aq)
The equilibrium constant Kc is 1×1016.
(Figure 1)

Part A

Calculate the equilibrium concentrations of CH3Cl, CH3OH, OH− and Cl− in a solution prepared by mixing equal volumes of 0.1 M CH3Cl and 0.5 M NaOH. (Hint: In defining x, assume that the reaction goes 100% to completion, and then take account of a small amount of the reverse reaction.)

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