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A solution of Na2CO3 is added dropwise to a solution that contains 1.21×10−2M Fe2+ and 1.48×10−2M...

A solution of Na2CO3 is added dropwise to a solution that contains 1.21×10−2M Fe2+ and 1.48×10−2M Cd2+ . What concentration of CO32− is need to initiate precipitation? Neglect any volume changes during the addition.

Express your answer with the appropriate units.

The solubility-product constants, Ksp , at 25 ∘C for two compounds [iron(II) carbonate, FeCO3 , and cadmium(II) carbonate, CdCO3 ] are given by the table

Substance Ksp
FeCO3 2.10×10−11
CdCO3 1.80× 10−14
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