Question

The solubility-product constants, Ksp, at 25 ∘C for two compounds [iron(II) carbonate, FeCO3, and cadmium(II) carbonate, CdCO3] are given by the table Substance Ksp FeCO3 2.10×10−11 CdCO3 1.80× 10−14

Part A Part complete A solution of Na2CO3 is added dropwise to a solution that contains 1.12×10−2 M Fe2+ and 1.53×10−2 M Cd2+. What concentration of CO32− is need to initiate precipitation? Neglect any volume changes during the addition. Express your answer with the appropriate units. View Available Hint(s) [CO32−] = 1.18×10−12 M SubmitPrevious Answers Correct Part B Part complete In the solution from Part A, what will the concentration of CO32− be at the moment before Fe2+ begins to precipitate? Express your answer with the appropriate units. View Available Hint(s) [CO32−] = 1.88×10−9 M SubmitPrevious Answers Correct Iron compound will begin to precipitate as soon as the following is met [Fe2+][CO32−]=2.10×10−11 Since [Fe2+] has a concentration of 1.12×10−2 M , you can substitute values to find [CO32−]. Depending on the magnitude of the differences in solubility, this concentration may result in both ions precipitating at the same time. Part C What will the concentration of Cd2+ at the moment before Fe2+ begins to precipitate? Express your answer with the appropriate units.

Answer 1