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Can you think of a situation that someone in a research lab might want to know...

Can you think of a situation that someone in a research lab might want to know about that would be made difficult or impossible because of poor shimming?

An individual used pentane as the solvent for NMR insted of deuterated pentane. This did so because pentane was avaliable and on hand, and deuterated pentane was more expensive. Why is deuterated pentane more expensive?

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