Question

Why is there no axial Cu-F or Cu-O interaction in the complexes [Cu(deen)2](BF4)2 or [Cu(deen)2](ClO4)2 as...

Why is there no axial Cu-F or Cu-O interaction in the complexes [Cu(deen)2](BF4)2 or [Cu(deen)2](ClO4)2 as opposed to the [Cu(R-en)2]X2 complexes?

X = BF4^-1, ClO4^-1, and NO3^-1

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Answer #1

When the groups comes at axial position then the strain is released and the groups cu-o and cu-f are becomes 90degree angle to each other ..Hence there are no axial interaction

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