Iron tablets may be used in the treatment of anaemia. To analyse the iron(II) content of commercially available iron tablets, a student used four tablets, each of mass 0.360 g to make up 250 mL of solution in a volumetric flask using dilute sulfuric acid and deionized water. About 15.0 mL of dilute sulfuric acid was added to a 25.0 mL portion of this iron(II) solution and the mixture then titrated with a 0.01025 M solution of potassium manganite(VII), KMnO4. In the titration the manganite(VII) is reduced to manganite(II) and the iron(II) is oxidized to iron(III). If the titration required 13.85 mL of the KMnO4 solution, calculate
(i) the concentration of the iron(II) solution in moles per liter. Ans: moles L-1
(ii) the mass of iron(II) in one tablet. Ans: g
(iii) the percentage by mass of iron(II) in each tablet. Ans: %
Iron tablets may be used in the treatment of anaemia. To analyse the iron(II) content of...
A solution of iron (II) sulfate was prepared by dissolving 10.00g of FeSO4-7H20 (FW= 277.9) in water and diluting up to a total volume of 250 ml. The solution was left to stand, exposed to air, and some of the iron (II) ions became oxidized to Iron (III) ions. a 25.0 ml sample of this partially oxidized solution required 23.70 ml of 0.0100M potassium dichromate K2Cr2O7 solution for complete reaction in the presence of dilute sulfuric acid. Calculate the percentage...
A sample of iron ore weighing 0.2962 g was dissolved in an excess of a dilute acid solution. All the iron was first converted to Fe(II) ions. The solution then required 23.70 mL of 0.0214 M KMnO4 for oxidation to Fe(III) ions. Calculate the percent by mass of iron in the ore. ___% by mass of Fe
II. Digestion of Acetylsalicylic acid(standard and tablet) with NaOH . Digestion of Acetylsalicylic Acid Standard to Prepare Stock Solution: Obtain ca. 0.1 g dried acetylsalicylic acid (MM = 180.16 g/mol), accurately weighed, and quantitatively transfer to a 125-ml Erlenmeyer flask. Add 5 ml 1.0 M NaOH and heat mixture to boiling on a hot plate. This will hydrolyze the acetylsalicylic acid to sodium salicylate. If necessary, rinse down the walls of the Erlenmeyer with DI water to ensure complete hydrolysis...
Potassium permanganate (KMnO4) solutions are used for the determination of iron in samples of unknown concentration. As a laboratory assistant, you are supposed to prepare 1500. mL of a 0.400 M KMnO4 solution. What mass of KMnO4, in grams, do you need? After, What is the molar concentration of a solution of sulfuric acid, H2SO4, if 5.95 mL react completely with 0.132 g of NaOH which was dissolved in enough water to make 200.mL of solution?
Calculate the content of an Iron(II)-solution in (g/l) (under the confidence interval of 95%) at a titration of 50 ml strong acidic solution with KMnO4-solution (0.1 mol/l). Volume used : 24.1 ml , 23.9 ml , 23.8 ml , 24.0 ml. midpoint: x̄=23.95 ml standard deviation: s = sqrt( sum(x-x̄)^2 / n-1)= 0.129 s95% = +/- 0.129 * t(95%,3) = +/- 0.129 * 3.18 = +/- 0.41 ml Volume = 23.95 +/- 0.41 ml What should be done afterwards?
THE DETERMINATION OF IRON BY SPECTROPHOTOMETRY INTRODUCTION In this experiment, the red-orange colored complex formed between iron(II) and 1,10- phenanthroline (Eqn.) is used in determination of iron by spectrophotometry. Fe+3PhenH Fe(Phen)2 +3H red-orange (A 512 nm) An excess of reducing reagent, such as hydroxylamine or hydroquinone, is often used to reduce and maintain iron in +2 oxidation state. The complex, once formed, is very stable, and can be stored for a long time. Required Reading: Skoog and West (9E): Chapter...
QUESTION 1 Minnie Mouse did the Ka by Titrimetry experiment last week. Minnie used 28.63 mL of 0.136 M sodium hydroxide to reach the equivalence point when she titrated 0.3062 g of an unknown monoprotic acid. What is the number of moles of acid that were used? QUESTION 2 The Iron in a sample of iron ore can be converted completely to Fe2+ in aqueous solution, and this solution can then be titrated with KMnO4, as shown: MnO4(q) + 6...
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ii) Nickel analysis - Prepare three standard nickel solutions using the following procedure. Accurately weigh approximately 1.0 g of [Ni(H20)6]504 into a 50 mL volumetric flask. Add 10 mL of D.I. water followed by 10 mL of 1 M H2SO4(aq) to dissolve the salt and then dilute to the mark with deionized water. Pipet 10 mL of the solution into one 25...
based on data please help fill out chart and questions
1,2,3
Part II: Neutralization of the Tablet 1. Obtain one of the commercial antacid tablets that your Lab Instructor has assigned you. 2. Weigh and record the weight of the tablet. 3. Crush the tablet using mortar and pestle. 4. Transfer as much of the crushed tablet as you can onto a weigh boat. 5. Weigh the tablet and weigh boat, and record this value. 6. Pour the entire contents...
used to titrate a solution of iron(II) ions., with which it reacts according to Cerium(IV) sulfate Ce4(aq)Fe2 (aq)>Ce3*(aq) + Fe3 (aq) A cerium(IV) sulfate solution is prepared by dissolving 40.47 g of Ce(SO42 in water and diluting to a total volume of 1.000 L. A total of 19.41 mL of this solution is required to reach the endpoint in a titration of a 100.0-mL sample containing Fe(aq). Determine the concentration of Fe2 in the original solution It is desired precipitate,...