The )G01 for the hydrolysis of phosphorarginine reaction depicted below is –32 kJ mol-1. Phosphoarginine ...
- The )G01 for the hydrolysis of phosphorarginine reaction depicted below is –32 kJ mol-1.
Phosphoarginine + H2O → Arginine + Pi
What is the free-energy change, )G, for the reaction in lobster muscle at 5oC and pH 7.0 when the concentrations of phosphoarginine, arginine and Pi are 6.1mM, 2.4mM and 5.7mM, respectively?
(R = 8.315 J/molK)
Homework Answers
For given reaction
Q = [arginine] [Pi] / [Phosphoarginine] = 2.4mM * 5.7 mM / 6.1mM = 2.2 mM
G =Go +
RT ln Q = -32 kJ/mol + (8.315 J/mol.K * 273 K)ln
(2.2*10-3) = -32 kJ/mol -13,847.22 J/mol
G = -32 kJ/mol
-13.8 kJ/mol = -45.8 kJ/mol
Add Answer to:
The )G01 for the hydrolysis of phosphorarginine
reaction depicted below is –32 kJ mol-1.
Phosphoarginine ...
Please help with this question about Gibb's free energy. The answer is: -47.6 kJ/mol. Please show...
Please help with this question about Gibb's free energy. The
answer is: -47.6 kJ/mol. Please show steps on how to find this
answer!
1) In a rat hepatocyte, the concentrations of ATP, ADP and Pi are 3.4 mM, 1.3 mM and 4.8 mM, respectively. ATP + H2O → ADP + Pi + H+ a) Calculate the actual Gibb's free energy change for hydrolysis of ATP in this cell. ([H2O) = 1M; [H+] = 1M; R = 8.315 JK-mol-1; T =...
2. Hydrolysis of 0.5 M studentose catalyzed by teacherase to become successose is 95% complete at...
2. Hydrolysis of 0.5 M studentose catalyzed by teacherase to become successose is 95% complete at equilibrium (i.e., only 5% of the studentose remains). What is AG"? (R = 8.315 J/mol K; T = 298 K) 3. The standard free-energy changes for the reactions below are given. Phosphocreatine creatine + Pi AG"=-43.0 kJ/mol ATP → ADP + Pi AG" = -30.5 kJ/mol The overall AG" for the reaction: Phosphocreatine + ADP creatine + ATP, is _ A) -73.5 kJ/mol C)...
er at initial change (AG The standard free energy change (AG) for ATP hydrolysis is -30.5 kJ/ mol ATP, ADP, and I a...
er at initial change (AG The standard free energy change (AG) for ATP hydrolysis is -30.5 kJ/ mol ATP, ADP, and I are mixed together at initial concentrations of 1 M each then left alone until the reaction below has come to equilibrium. For each species (ie. ATP. ADP and P.) indicate whether the concentration will be equal to 1 M, less than 1 M, or greater than 1 M after the reaction had reached equilibrium. Explain why. ATP +...
Consider the hydrolysis of ATP: ATP(aq) + H2O(l) → ADP(aq) + Pi(aq). This reaction has ΔH°=...
Consider the hydrolysis of ATP: ATP(aq) + H2O(l) → ADP(aq) + Pi(aq). This reaction has ΔH°= −24.3 kJ/mol and ΔS°= +21.6 J/mol-K. The actual concentrations of ATP, ADP, and Pi are not 1 M in a biological cell. How much energy can the conversion of ATP to ADP supply when it occurs at physiological conditions in E. coli where the temperature is 37°C and the approximate concentrations are ATP = 11.2 mM, ADP = 1.52 mM, Pi = 20.0 mM?...
A reaction has a standard free-energy change of -4.78 kJ/mol at 25 degree C. What are...
A reaction has a standard free-energy change of -4.78 kJ/mol at 25 degree C. What are the concentrations of A, B, and C at equilibrium if, at the beginning of the reaction, their concentrations are 0.30 M, 0.40 M, and 0 M, respectively? How would your answers above change if the reaction had a standard free-energy change of +4.97 kJ/mol? All concentrations would be higher. All concentrations would be lower. There would be no change to the answers. There would...
We have seen all term that cells use the hydrolysis of high energy phosphate from ATP...
We have seen all term that cells use the hydrolysis of high energy phosphate from ATP to make metabolic reactions thermodynamically favorable. Whereas most enzymes that utilize ATP hydrolyze between the b and g phosphates (yielding ADP + Pi), some enzymes hydrolyze ATP between the a and b phosphates (yielding AMP and PPi). ∆G°’ of phosphate hydrolysis is -31 kJ/mol for ATP + H2O --> ADP + Pi, and ∆G°’ of phosphate hydrolysis is -46.5 kJ/mol for ATP + H2O...
A reaction A(aq) + B(aq) = C(aq) has a standard free-energy change of -3.06 kJ/mol at...
A reaction A(aq) + B(aq) = C(aq) has a standard free-energy change of -3.06 kJ/mol at 25 °C. What are the concentrations of A, B, and C at equilibrium if, at the beginning of the reaction, their concentrations are 0.30 M, 0.40 M, and 0 M, respectively? How would your answers change if the reaction had a standard free-energy change of +3.06 kJ/mol? O There would be less A and B but more C. All concentrations would be higher. There...
A reaction has a standard free-energy change of-489 kJ/mol at 25 °C. What are the concentrations...
A reaction has a standard free-energy change of-489 kJ/mol at 25 °C. What are the concentrations concentrations are 0.30 M, 0.40 M, and 0 M, respectively? of A, B, and C at equilibrium if, at the beginning of the reaction, their Number Number Number How would your answers above change if the reaction had a standard free-energy change of +4.89 kJ/mol? O There would be no change to the answers. O All concentrations would be higher. All concentrations would be...
A reaction Alaq) + Blaq) = Claq) has a standard free-energy change of -3.44 kJ/mol at...
A reaction Alaq) + Blaq) = Claq) has a standard free-energy change of -3.44 kJ/mol at 25°C. What are the concentrations of A, B, and C at equilibrium if, at the beginning of the reaction, their concentrations are 0.30 M, 0.40 M, and 0 M, respectively? Number Number Number [A]= M [B] = [c]= 0 How would your answers above change if the reaction had a standard free-energy change of +3.44 kJ/mol? O O All concentrations would be lower. All...
A reaction A(aq) + B(aq) = C(aq) has a standard free-energy change of -3.38 kJ/mol at...
A reaction A(aq) + B(aq) = C(aq) has a standard free-energy change of -3.38 kJ/mol at 25°C. What are the concentrations of A, B, and C at equilibrium if, at the beginning of the reaction, their concentrations are 0.30 M, 0.40 M, and OM, respectively? [A] = [B] = 1C) = How would your answers change if the reaction had a standard free-energy change of +3.38 kJ/mol? There would be no change to the answers. O All concentrations would be...
Please help with this question about Gibb's free energy. The
answer is: -47.6 kJ/mol. Please show steps on how to find this
answer!
1) In a rat hepatocyte, the concentrations of ATP, ADP and Pi are 3.4 mM, 1.3 mM and 4.8 mM, respectively. ATP + H2O → ADP + Pi + H+ a) Calculate the actual Gibb's free energy change for hydrolysis of ATP in this cell. ([H2O) = 1M; [H+] = 1M; R = 8.315 JK-mol-1; T =...
2. Hydrolysis of 0.5 M studentose catalyzed by teacherase to become successose is 95% complete at equilibrium (i.e., only 5% of the studentose remains). What is AG"? (R = 8.315 J/mol K; T = 298 K) 3. The standard free-energy changes for the reactions below are given. Phosphocreatine creatine + Pi AG"=-43.0 kJ/mol ATP → ADP + Pi AG" = -30.5 kJ/mol The overall AG" for the reaction: Phosphocreatine + ADP creatine + ATP, is _ A) -73.5 kJ/mol C)...
er at initial change (AG The standard free energy change (AG) for ATP hydrolysis is -30.5 kJ/ mol ATP, ADP, and I are mixed together at initial concentrations of 1 M each then left alone until the reaction below has come to equilibrium. For each species (ie. ATP. ADP and P.) indicate whether the concentration will be equal to 1 M, less than 1 M, or greater than 1 M after the reaction had reached equilibrium. Explain why. ATP +...
A reaction A(aq) + B(aq) = C(aq) has a standard free-energy change of -3.06 kJ/mol at 25 °C. What are the concentrations of A, B, and C at equilibrium if, at the beginning of the reaction, their concentrations are 0.30 M, 0.40 M, and 0 M, respectively? How would your answers change if the reaction had a standard free-energy change of +3.06 kJ/mol? O There would be less A and B but more C. All concentrations would be higher. There...
A reaction has a standard free-energy change of-489 kJ/mol at 25 °C. What are the concentrations concentrations are 0.30 M, 0.40 M, and 0 M, respectively? of A, B, and C at equilibrium if, at the beginning of the reaction, their Number Number Number How would your answers above change if the reaction had a standard free-energy change of +4.89 kJ/mol? O There would be no change to the answers. O All concentrations would be higher. All concentrations would be...
A reaction Alaq) + Blaq) = Claq) has a standard free-energy change of -3.44 kJ/mol at 25°C. What are the concentrations of A, B, and C at equilibrium if, at the beginning of the reaction, their concentrations are 0.30 M, 0.40 M, and 0 M, respectively? Number Number Number [A]= M [B] = [c]= 0 How would your answers above change if the reaction had a standard free-energy change of +3.44 kJ/mol? O O All concentrations would be lower. All...
A reaction A(aq) + B(aq) = C(aq) has a standard free-energy change of -3.38 kJ/mol at 25°C. What are the concentrations of A, B, and C at equilibrium if, at the beginning of the reaction, their concentrations are 0.30 M, 0.40 M, and OM, respectively? [A] = [B] = 1C) = How would your answers change if the reaction had a standard free-energy change of +3.38 kJ/mol? There would be no change to the answers. O All concentrations would be...
Most questions answered within 3 hours.
-
Where is the error in this code sequence?
String s1 = "Hello";
String s2 = "ello";...
asked 11 months ago -
Financial data for Joel de Paris, Inc., for last year
follow:
Joel de Paris, Inc.
Balance...
asked 11 months ago -
Consider this reaction:
Al2(SO4)3 (aq)+ BaCl3
(aq) Al2Cl6 (aq)- +
3BaSO4(s) . What is the...
asked 11 months ago -
Suppose that Savneet is considering increasing her
recent random sample from 20 car rentals to 40...
asked 11 months ago -
Trucks arrive at an unloading terminal at an average rate of 120
per hour.
Trucks arrive...
asked 11 months ago -
Why are methanol and ethanol completely soluble in water while
octanol is not very little soluble....
asked 11 months ago -
A facilities manager at a university reads in a research report
that the mean amount of...
asked 11 months ago -
When the CuSO4 is rehydrated by adding water to the anhydrous
compound, is this an endothermic...
asked 11 months ago -
A ray of sunlight is passing from diamond into crown glass; the
angle of incidence is...
asked 11 months ago -
A block of mass 0.249 kg is placed on top of a light, vertical
spring of...
asked 11 months ago -
how do the kidneys compensate in the presences of acidosis
a) trigger hyperventilate
b) reserve acid...
asked 11 months ago -
Question 501 pts
The rental rate of capital to the firm increases. Which of the
following...
asked 11 months ago