The lead contained in a 0.2000 g sample is precipitated as PbCrO4. The precipitate is filtrated, washed and re-dissolved in acid to give lead ions and dichromate. 15.00 mL of 0.100 M FeSO4 is required to titrate the dichromate to the end point. Calculate the percentage of lead in the original sample.
Pb2+ + 2 CrO42- ===> PbCrO4(s)
2 PbCrO4 + 2 H+ ===> 2 Pb2+ + Cr2O72- + H2O
Cr2O72- + 6 Fe2+ + 14 H+ ===> 2 Cr3+ + 6 Fe3+ + 7 H2O
asnwer should be around 50%
The lead contained in a 0.2000 g sample is precipitated as PbCrO4. The precipitate is filtrated,...
Lead ions can be precipitated from aqueous solutions by the addition of aqueous iodide: Pb2+(aq) + 2 I-(aq) → PbI2(s) Lead iodide is virtually insoluble in water so that the reaction appears to go to completion. How many milliliters of 3.550 M HI(aq) must be added to a solution containing 0.100 mol of Pb(NO3)2 to completely precipitate the lead?
A person's blood alcohol (C2H5OH) level can be determined by titrating a sample of blood plasma with a potassium dichromate solution. The balanced equation is 16 H+(aq) + 2 Cr2O72-(aq) + C2H5OH(aq) 4 Cr3+(aq) + 2 CO2(g) + 11 H2O(l) If 30.78 mL of 0.05958 M Cr2O72- is required to titrate 27.22 g plasma, what is the mass percent of alcohol in the blood plasma?
A 4.298 g sample of the mineral tellurite (TeO2) was dissolved in acid. A 50.00 mL volume of a 0.02842 M K2Cr2O7 solution was added. 3 TeO2 s+ Cr2O72- aq+8 H+ aq3 H2TeO4 aq+2 Cr3+ aq+H2O l When the reaction is complete, the excess Cr2O72– is back-titrated, requiring 13.76 mL of 0.1062 M Fe2+ to reach the end point. a) Use appropriate half-reactions to write the balanced reaction equation for the back-titration of the excess Cr2O72– with Fe2+. (3 pts)...
3. A1.22 g solid sample of impure lead (11) nitrate was dissolved in 40.0 mL of distilled water and analyzed by gravimetric analysis. Sodium sulfate was delivered from a burette to precipitate the lead ions as lead sulfate. Sodium sulfate was added until no more precipitate was seen to form. The precipitate was filtered, washed an dried before been weighed. When weighed, the precipitate had a mass of 1.44 g. What is the mass percent of lead in the original...
1. A solid sample containing some Fe2+ weighs 2.360 g. It required 36.44 mL 0.0244 M KMnO, to titrate the Fe- in the dissolved sample to a pink end point. The balanced redox reaction is shown below. 8 H + MnO4 + 5 Fe2+ + Mn2+ + 5 Fe3+ + 4H20 Calculate each of the following quantities. 2. (2 points) Calculate the percentage of Fe in pure iron(II) ammonium sulfate hexahydrate: (NH4)2[Fe(SO4)2]• 6 H20.
1. A 0.4187 g sample of a pure soluble chloride compound is dissolved in water, and all of the chloride ion is precipitated as AgCl by the addition of an excess of silver nitrate. The mass of the resulting AgCl is found to be 0.9536 g. What is the mass percentage of chlorine in the original compound? ________% 2. A student determines the calcium content of a solution by first precipitating it as calcium hydroxide, and then decomposing the hydroxide...
Please help. I will rate!
A 0.4721 g sample of pewter, containing tin, lead, copper, and zinc, was dissolved in acid. Tin was precipitated as SnO 4 H,O and removed by filtration. The resulting filtrate and washings were diluted to a total volume of 250.0 mL. A 15.00 mL aliquot of this solution was buffered, and titration of the lead, copper, and zinc in solution required 34.45 mL of 0.001518 M EDTA. Thiosulfate was used to mask the copper in...
I concluded that my unknown was Pb2+. since yellow
precipitate formed. can you help me answer the questions for the
Known and unknown report
Qualitative Analysis: Group I Cations 10 ORECTIVES A Leam some chemistry of Group I cations, R Analyze an unknown for Group I cations. THEORY AND DISCUSSION Group I cations are precipitated as insoluble chlorides: Ag, Pb, Hg2 +Cr-AgCl, PbCh, HgCla The colors of the following species will be helpful in the analysis for Group I cations....
1. If your original unknown is colorless, what ions are absent
from your unknown?
2. If you get no precipitate with just the 6 M NH3 in step B,
what ions are absent from your unknown?
pls help are my answers correct ty
17 Page 4 Aperiment 24. Qualitative Analysis Group III-NI, Mn, Fe, Al, Cr, Zn 1. PROCEDURES A. Observations of Samples. Obtain an unknown and record code. Observe color of unknown solution Common color correlations are: dark blue...
Question 1 (1 point) A 52.30 g sample of Ba(OH)2 is dissolved in enough water to make 1.20 L of solution. How many milliliters of this solution must be diluted with water in order to make 1.00 L of 0.100 M Ba(OH)2? 62.8 mL 254 mL O 305 ml O 523 mL O 393 mL O Question 2 (1 point) A chemist needs 225 mL of 2.3 M HCl. What volume of 12 M HCl must be dissolved in water...