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Phosgene (carbonyl chloride), COCl2, is an extremely toxic gas that is used in manufacturing certain dyes...

Phosgene (carbonyl chloride), COCl2, is an extremely toxic gas that is used in manufacturing certain dyes and plastics. Phosgene can be produced by reacting carbon monoxide and chlorine gas at high temperatures: CO(g)+Cl2(g)⇌COCl2(g) Carbon monoxide and chlorine gas are allowed to react in a sealed vessel at 465 ∘C .

At equilibrium, the concentrations were measured and the following results obtained:

Gas Partial Pressure (atm)

CO 0.840

Cl2 1.10

COCl2 0.250

What is the equilibrium constant, Kp, of this reaction? Express your answer numerically.

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Answer #1

CO(g)+Cl2(g)⇌COCl2(g)

PCO   = 0.84atm

PCl2    = 1.10atm

PCOCl2   = 0.25atm

Kp    = PCOCl2/PCO* PCl2

         = 0.25/0.84*1.10   = 0.27 >>>>>> answer

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