For the following exothermic reaction at equilibrium
A(g) + B(g) ⇌ C(g)
Which of the following conditions will cause the reaction to produce more products?
Select as many answers as are appropriate however marks will be deducted for incorrect guesses.
Select one or more:
Increasing the volume
Increasing partial pressure of "A"
Raising the temperature
Decreasing the volume
Increasing partial pressure of "C"
Increasing partial pressure of "B"
Lowering the temperature
Answers:
Increasing partial pressure of A
Decreasing volume
Increasing partial pressure of B and
Lowering temperature.
Explanation:
Kp= pc/(pa)(pb)
Now Kp for a reaction is always constant at a particular temperature. Hence, if we increase partial pressure of A or B the reaction will shift forward to compensate the partial pressure of C to a value required to mainatim Kp constant.
On decreasing volume pressure of all the components will drop and if that happens we can see that the denominator term in Kp will decraedewith more extent. Now, to maintain the Kp value same the reaction will shift forward to increase pressure of C.
And exothermic reaction always moves forward on decraeside temperature and vice versa.
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