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1HNMR is a carbonyl group more de-shielding than a C-O? which one would cause the furthest...

1HNMR is a carbonyl group more de-shielding than a C-O? which one would cause the furthest upfield signal?

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Answer #1

The protons which are directly attached with carbonyl group are highly deshielded due to the diamagnetic anisotropy of carbonyl group whereas for the protons which are attached with a carbon (adjacent of Oxygen atom) are only deshielded by the electronegativity of Oxygen atom

Thus former will show the furthest upfield signal.

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