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A solution consists of 45.50g naphthalene (a non-volatile compound, MW=128.17g/mol) dissolved in 50.00g of ethanol (MW=46.02g/mol)....

A solution consists of 45.50g naphthalene (a non-volatile compound, MW=128.17g/mol) dissolved in 50.00g of ethanol (MW=46.02g/mol). The vapor pressure of pure ethanol at 25.0°C is 96.0 mmHg. What is the vapor pressure of the solution at 25.0°C?

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Answer #1

The vapor pressure of ethanol = 96.00 mm Hg

Moles of naphthalene = mass / molar mass

                          = 45.50 g/ 128.17 g/mol

                          = 0.355 moles

Mass of ethanol = 50 g

Moles = 50 g / 46.02 g/mol

          = 1.086 moles

The mole fraction of ethanol = moles of ethanol / total moles

                                   = 1.086moles / 1.441 moles

                                   = 0.754

The vapor pressure of solution with a nonvolatile solute

= Pure vapor pressure * mole fraction of solvent

= 96 mm Hg * 0.754

=72.38 mm Hg

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