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why the intensity of stokes line decrease when the temperature is increase? why the intensity of...

why the intensity of stokes line decrease when the temperature is increase?
why the intensity of anti-stokes line increase when the temperature is increase?
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Answer #1

Both have the same reason. Temperature rise would decrease the population of the ground state and increase the population of higher energy vibrational states. Therefore, with increased temperature, the intensity of the Stokes lines would decrease and the intensity of the anti-Stokes lines would increase

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