Calculate the Eh for (a) acid mine drainage (pH = 4) and (b) ocean water (pH = 8.3), in equilibrium with atmospheric oxygen (assume pO2 = O2 fugacity = 0.2 bar) at 25 °C.
Eh = 1.23 + 0.01479 log10[O2] – 0.05916 pH. [O2] = oxygen fugacity. (3 pts)
Calculate the Eh for (a) acid mine drainage (pH = 4) and (b) ocean water (pH...
2. A water sample is taken from a stream in Nevada receiving acid mine drainage. The stream passes through an area containing gypsum CaSO4. Laboratory analysis shows that the pH of the water is 4, the total concentration of sulfate (SO42-) is 6 x 10-M, and the total concentration of chloride (C1) is 3 x 10-4M. a) Assuming that the only other ionic species present is calcium (Ca?), what is the calcium concentration in the water?
4. Some treatment techniques for acid mine drainage rely on the use of sulfate-reducing bacteria to convert sulfuric acid to H2S in order to reduce corrosivity. Sulfate-reducing bacteria obtain energy by the following reaction: 7H+ + CH3C00- + S0 + 2H2CO3(aq) + H2Saq + 2H20 a. (10 points) Calculate the standard free energy change for the reaction as written b. (8 points) Calculate the equilibrium constant at 25°C for the reaction as written
4. Calculate the pH of a solution of pure water containing 1.0 mg/L of sulfuric acid.
1. Calculate the pH at 25°C of a 0.757 M solution of a weak acid that has Ka = 9.28 x 10 2. Determine the Kb of a weak base if a 2.50 M solution of the base has a pH of 9.595 at 25°C. 3. The overall dissociation of malonic acid, H2C3H2O4, is represented below. The overall dissociation constant is also indicated. H2C3H204 = 2 H+ + C3H2042- K = 3.0 x 10-9 To a 0.025-molar solution of malonic...
1. Calculate the pH of a 0.0820 M solution of the acid HClO dissolved in water if Ka = 2.9x10-8. 2. Calculate the pH of a 0.4480 M solution of the base H2BO3-1 dissolved in water if Ka = 5.4x10-10 for H3BO3. 3. Calculate the pH of a solution containing the following compounds. (Note that these are concentrations before any reaction occurs). [NaH2PO4] 0.300 M [Na2HPO4] 0.840 M [KOH] 0.054 M 4. For the titration of 15.00 mL of 0.100...
due to
1) You are in charge of a remediation strategy that requires aerobic, microbial respiration to degrade the compound ethanol in groundwater. There is 840mg/L ethanol in the groundwater; how much oxygen (total, steady state concentration in mg/L) will you need to completely oxidize the ethanol to CO2? Can you accomplish this using only atmospheric oxygen (21 % v/v) at 1 atm total pressure (Pro) and 25°C? If you cannot, what options do you have for increasing oxygen content...
please show full work for understanding purposes:)
5. (4 pts) Calculate the pH of a 0.0025 M aqueous solution of strontium hydroxide, Sr(OH). Sr(OH)2 = Srz + 20H .0025 - x + x + 2x o rood .0025 - Kb = (2x² 4 = 6.5*103 0.0025 ) pH = 6. (6 pts) Calculate the pH of a 0.175 M NH; aqueous solution. K. for NH, is 1.8 x 10. pH = 180 7. (10 pts) Determine the pH of a...
QUESTION 11 Calculate the pH for an aqueous solution of acid that contains 2.15 x 10-3 M H30 at equilibrium. A. 4.65x 10-12 B. 2.15 x 10-3 11.33 Oc OD. 2.67 QUESTION 12 Calculate the pH for an aqueous solution that contains 2.15 x 10-3 M OH at 25 °C A. 4.65 x 10-11 B.2.15x 10-4 O c.3.67 OD. 11.33
Formic acid (HCO2H) has a Ka value of 1.70 X 10-4 at 25°C. Calculate the pH at 25°C of . . . . a. a solution formed by adding 15.0 g of formic acid and 30.0 g of sodium formate (NaCO2H) to enough water to form 0.500 L of solution. b. a solution formed by mixing 30.0 mL of 0.250 M HCO2H and 25.0 mL of 0.200 M NaCO2H and diluting the total volume to 250 mL. c. a solution...
1. Calculate the pH of 1.0 M monochloroacetic acid (HCHCIO) with a K, of 1.35x10 (10 points. HCq Ha Cload Catz (102H 0 & X y X 0 2. Calculate the erams of sodium sorbate (NaCsH-CO) required to make 1.00 liter of a 0.0860M sorbic acid solution pH 3.80. The K, for sorbic acid is 1.70 x10 (10 points). 3. A 25.0 mL sample of 0.120 M of lactic acid (HCH.0.) is titrated with 25.0 mL of sodium hydroxide to...