Question

Write a balanced equation for the following synthesis. a) synthesis of [Mn(acac)3] / reactants: KMnO4, H2O,...

Write a balanced equation for the following synthesis.

a) synthesis of [Mn(acac)3] / reactants: KMnO4, H2O, and acytylacetone

b) synthesis of [Cr(acac)3] / reactants: chromium(III) chloride hexahydrate, urea, H2O, and acytylacetone

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Answer #1

a) synthesis of [Mn(acac)3] / reactants : KMnO4, H2O, and acytylacetone .. MnCl2 is missing

The balanced equation is

4 MnCl2.H2O + KMnO4 + 15 (Hacac) ----------> 5 Mn(acac)3 + 20 H2O + 7 HCl + KCl

* Hacac = acetylacetone = C5H8O2

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b) Synthesis of [Cr(acac)3]

The balanced equation is

CrCl3.6H2O + 2 NH2CONH2 + 3 Hacac ------------> Cr(acac)3 + 2 CO2 + 4 NH4+ + OH- + 3 Cl- + 3 H2O

NH2CONH2 = urea

CrCl3.6H2O = chromium(III) chloride hexahydrate

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