|
Species |
DHf (kJ/mol) |
DSf (J/ (mol *K) |
|
NH4NO3(s) |
-365.56 |
151.08 |
|
NH4+(aq) |
-132.51 |
113.4 |
|
NO3-(aq) |
-205.0 |
146.6 |
Consider the following data at 300 K for the reaction NH4NO3(s) « NH4+(aq) + NO3-(aq) Species...
Given the information below, what is AGº for the reaction: NH4NO3(s) - NH4+ (aq) + NO3(aq) AH (kJ/mol) S° (J/molk) NH4NO3(s) -365.56 151.08 NH4 (aq) -132.51 113.4 NO3(aq) -205.0 146.4 +32.3 kJ -80.7 kJ -4.34 kJ O none of these
I am having a heck of a time understanding these. If you could explain the steps that would be wonderful! a. If the reaction above (c) were conducted at 273K with [NH4+] = 0.34M and [NO3-] = 0.12M, what would be the value of ΔG? Would the reaction be spontaneous in the forward or reverse direction? b. Should CrCl3 be more soluble in a solution buffered at pH = 5.5 or pH = 9.5, given that it forms the complex...
Consider the following reaction. NH4NO3(s) ⇌ NH4+(aq) + NO3–(aq) ΔH > 0 If the temperature is increased, what happens to the values of Q and K? In which direction will the equilibrium shift, if at all?
3) The dissociation of ammonium nitrate in aqueous solutions is described by the following chemical reaction Use the information provided in the table below at 25°C, to plot the Gibbs free energy change as a function of the natural logarithm of Q, InQ. [Recall that Q is the quotient of the product of the products raised to the stoichiometric coefficients over the product of the reactants raised to their stoichiometric coefficients.] a) On the ΔG vs In(Q) plot indicate the...
Determine the standard entropy change of the universe when 0.3 mol of NH4NO3 is produced, NH4 (aq) NO3(aq) NH4NO3(s), given the following information. (answer in J/K) AH (kJ/mol) S°(J/mol K) Substance NH4NO 3(s) -365.6 151.1 NH4 (aq) -132.5 113.4 NO 3 (aq) -205.0 146.4 Answer: 1575.1 Check
NH4NO3 (s)
NH4+ (aq) + NO3-
(aq)
H°f
NH4NO3 (s) = -365.6 kJ/mol
H°f
NH4NO3 (aq) = -339.9 kJ/mol
What is
H°rxn?
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Determine the standard entropy change of the universe when 0.2 mol of NH,NO3 is produced, NH4+ (aq) + NO3-(aq) --NH.NO3(s), given the following information. (answer in J/K) Substance NH.NO3(s) AH!"(kJ/mol) SºU/molK) -365.6 151.1 -132.5 113.4 -205.0 146.4 NH" (G) NO3(aq) Answer: Check
please show work and maybe explanations ?
Practice Problem 1 Calculate AH and AS for the following reaction (the Haber process for the manufacture of ammonia) and calculate if the reaction is favorable at STP. N2(g) + 3 H2(g) 2 NH3(g) (The following information may also be obtained from Appendix C in the Jespersen text.) Compound Enthalpy (kJ/mol) Entropy (J/mol-K) N2(9) H2(g) NH3(g) 0 191.61 130.68 192.45 -46.11 Practice Problem 2 Use the values of AH and AS calculated in...
1.) NH4NO3(s) ↔ NH4+(aq) + NO3-(aq) +17 kJ/mol what is K at room temp? A)0.993 B)1.00 C)1.05 x 10-3 D)954 2.) For the following reactions: 2NH3(g) 3H2(g) + N2(g) What is under the following conditions: T = 25oC PNH3 = 12.9 atm PH2 = 0.250 atm PN2 = 0.870 atm A) 33 kJ/mol B) 56 kJ/mol C) 10 kJ/mol D) 31 kJ/mol
The dissolution of ammonium nitrate is given by the reaction: NH4NO3 (s) ----> NH4+ (aq) + NO3- (aq) Assuming that the values of ΔH° and ΔS° do not change appreciably with temperature, calculate the ΔG° value for the reaction from the polyatomic ion data in standard thermodynamic property tables. ΔG°: -4.1 kJ Predict the lowest temperature at which the reaction is spontaneous. T= _____ degrees Celsius