Butadiene reacts to form its dimer according to the
equation
2 C 4H6(g) --> C8H12(g)
The following data were collected for this reaction at a given
temperature:
[C4H6] Time ( 1 s)
0.01000 0
0.00625 1000
0.00476 1800
0.00370 2800
0.00313 3600
0.00270 4400
0.00241 5200
0.00208 6200
(a) Determine is the order of this reaction? Write the rate law
expression. Justify your answer. Sketch a graph as part of your
explanation.
(b) Determine the value of the rate constant for this reaction?
(c) Determine the half-life for the reaction under the conditions
of this experiment?
2nd since plot of 1/[C4H6] vs. time yields a straight line with a
|slope| = k = 6.14 × 10−2 M/s; 1630 s
To find out rate of a reaction we have four different methods.
1) Graphical method
2) Half Life method
3) Initial rate method
4) Concentration V/S time method
I use Graphical and Concentration V/S time method simultaneously



Butadiene reacts to form its dimer according to the equation 2 C 4H6(g) --> C8H12(g) The...
Butadiene (C4H6) reacts with itself to form a dimer with the formula C8H12. The reaction is second order in C4H6. Assume the rate constant at a particular temperature is 4.0×10−2M−1s−1 and the initial concentration of C4H6 is 0.0250 M. A)What is its molarity after a reaction time of 1.10 h? B)What is the time (in hours) when the C4H6 concentration reaches a value of 0.0025 M?
Butadiene (C4H6)reacts with itself to form a dimer with the formula C8H12. The reaction is second order in C4H6. Assume the rate constant at a particular temperature is 4.0×10−2M−1s−1 and the initial concentration of C4H6 is 0.0230 MM. What is its molarity after a reaction time of 1.30 hh? What is the time (in hours) when the C4H6 concentration reaches a value of 0.0023 M?
Butadiene (C4H6) reacts with itself to form a dimer with the formula (C8H12). The reaction is second order in C4H6. If the rate constant at a particular temperature is 4.0×10−2M−1s−1. PART A) hat is the half-life (in minutes) of this reaction when the initial C4H6 concentration is 1.50×10−2 M ? Express your answer using two significant figures. PART B) How many minutes does it take for the concentration of C4H6 to drop from 1.20×10−2 M to 6.00×10−3 M ?
Review Constants Periodic Tab Part A Butadiene (C4H6) reacts with itself to form a dimer with the formula C8H12. The reaction is second order in C4H6. Assume the rate constant at a particular temperature is 4.0 x 10-2 M-18-1 and the initial concentration of C4H6 is 0.0180 M. What is its molarity after a reaction time of 1.30 h? Express your answer in moles per liter to two significant figures. Molarity = Submit Request Answer Part B What is the...
3. Butadiene (C4H) reacts with itself at 250 °C to form a dimer with the formula CxH12. 2 C.H. (g) →C3H12 (1) The reaction is second order in C4H. mC4H16. a) What is the rate law for the reaction? b) If initial concentration of C.H. is 0.400 M, what is the concentration of C&H, after 25 min if the rate constant is 4.0 x 10-2 M's?
PLEASE HELP WITH ENTIRE... 2: Consider the dimerization of C4H6: 2 C4H6 --> C8H12 for which the following data re collected: time (sec) [C4H6] (M) 0 1.00x10-2 1600 5.04x10-3 3200 3.37x10-3 4800 2.53x10-3 6200 2.08x10-3 A: Using empirical kinetics methods, determine the order of the reaction rate law. a 2nd order b 1st order c 0th order d The order can not be determined from this data. B: Based on the data above, calculate the concentration of C4H6 at 7,885...
1. Initial rate data at 25.0 °C are listed below for the reaction: 2 HgCl2 (aq) C2O (aq)2 C (aq)+ 2 CO:(g)+ Hg Cl(s) (COP)0 Expt. HgClalo Initial rate/ 3.1 x 10 1 0.100 0.20 1.2x 10 0.100 0.40 6.2x 10S 0.050 0.40 Use the data to determine the rate law for the reaction. 2. At 500 °C, cyclopropane (CsH6) rearranges to propene (CH3CH-CH2): CH CH=CH2 (g) CaHs (g) The reaction is first order and the rate constant is 6.7...
1: Consider the following set of data ccollected for a reaction of the form A --> products. time (seconds) [A] (M) 0 1.000 10 0.641 20 0.472 30 0.373 40 0.309 50 0.263 A: What is the average rate of the reaction for the first 10 seconds? rate = ___ M/s B: What is the average rate of the reaction between 30 and 40 seconds? rate = ___ M/s 2: Consider the dimerization of C4H6: 2 C4H6 --> C8H12 for...