Write the chemical names for the following compounds (if the metal is in a complex ion,...
Write the chemical names for the following compounds (if the metal is in a complex ion, be sure to include its oxidation number!)
a. Rb[AgF4]
b. fac-[Re(bpy)(CO)3Cl]
c. [Co(NH3)5(H2O)]SO4
d. [Ag(NH3)2][PF6]
e. mer-[Fe(H2O)3I3]
f. trans-[CoCl2(en)2]Cl
g. [Ni(bpy)3](NO3)2 h. Mo(CO)6
2. Sketch all optical and/or geometric isomers of the following:
a. [Pt(NH3)3Cl3] +
b. [PtCl2(en)2] 2+
c. Pt(NH3)2Cl2
Homework Answers
Chemical name of complexes:
Certain rules recommended by the International Union of Pure and Applied Chemistry (IUPAC) for naming of coordination compounds. By using that rules coordination complexes are named for given complexes.
Optical and geometrical isomerism:
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Write the chemical names for the following compounds (if the
metal is in a complex ion,...
Part A Which of the following pairs of coordination compounds or complex ions are examples of...
Part A Which of the following pairs of coordination compounds or complex ions are examples of ionization isomers? [Fe(NH3)2(H20)4]Cl2 and [Fe(NH3)4(H20)2Cl2 [Cu(CO)gBr]CI and [Cu(CO), CIJBr [MnCl3Br]2- and [MnCIBr312- [Fe(NH3)2(H20)4]C12 and [Fe(NH3)2(H20)4]Br2 [Fe(CO)NO12+ and [Fe(CO) ONO]2+ Submit Previous Answers Request Answer Part A Identify the isomers that have ligands that coordinate to a metal with different donor atoms. stereoisomers cis-trans isomers linkage isomers O coordination isomers O optical isomers Submit Request Answer Which of the following is a type of constitutional...
Complete the table Formula Structure Oxidation state of Metal Charges of complex d electron count [Ti(H2O)4Cl2]...
Complete the table Formula Structure Oxidation state of Metal Charges of complex d electron count [Ti(H2O)4Cl2] fac-[Mo(NH3)3(OH)3]+ trans-[Ni(H2O)2Cl2]2+ cis-[Cr(C2O4)2(py)2]2- delta-[Ni(acac)3]
Circle the pairs of compounds that are isomers of each other: (a) [Co(en)_3]Cl_3 and [Co(en)_3]Br_3 (b)...
Circle the pairs of compounds that are isomers of each other: (a) [Co(en)_3]Cl_3 and [Co(en)_3]Br_3 (b) [Co(H_2O)_4 Br_2]Cl and [Co(H_2O)_4BrCl]Br (c) [Cr(H_2O)_2(CO_3)_2]^2+ and [Cr(H_2O)_2(CO)_2(O_2)_2]^2+ (d) trans-[Pt(NH_3)_2Cl_2] and [Pt(NH_3)_3Cl]Cl Circle the appropriate description of the distinction between "geometric isomers" and "optical isomers": (a) Geometric isomers have a different set of bonds. optical isomers have the same set of bonds. (b) Geometric isomers differ in the spatial arrangement of bonds. In optical isomers the arrangement of bonds is the same. (c) Geometric...
Draw and label (cis/trans, fac/mer, linkage, optical, etc.) all unique isomers of the following coordination compound(s):...
Draw and label (cis/trans, fac/mer, linkage, optical, etc.) all unique isomers of the following coordination compound(s): b. [Pt(NH3)2(SCN)(Br)]
Complete table C.N is coordination number O.N is Oxidation number Complex Formula C.N O.N of the...
Complete table C.N is coordination number O.N is Oxidation number Complex Formula C.N O.N of the metal Cationic or anionic complex Name of metal complex K4[Ni(CN)4] [Cr(OH2)4Cl2]Cl Na3[Co(C2O4)3] [CoCl2(en)2]F [Co(P(CH3)3)4]2(SO4)3 [Fe(NH3)6]SO4 Na2[MoOCl4] [Cr (NH3)6]Cl3 [Zn(OH)4]-2 [V(OH2)6](NO3)3
Which of the following compounds can exhibit fac-mer isomerism? [V(NH3)2(H2O)4]2+ [Cu(CO)5I]+ [Cr(H2O)4Br2]+ [Ni(CO)5NO2]2+ [Fe(H2O)3(CO)3]3+
Which of the following compounds can exhibit fac-mer isomerism? [V(NH3)2(H2O)4]2+ [Cu(CO)5I]+ [Cr(H2O)4Br2]+ [Ni(CO)5NO2]2+ [Fe(H2O)3(CO)3]3+
Determine the oxidation state and coordination number of the metal ion in each complex ion. [Cu(CN)2]1-...
Determine the oxidation state and coordination number of the metal ion in each complex ion. [Cu(CN)2]1- [Ag(NH3)2]1+ [Cu(OH2)4]2+ [Pt(NH3)2Cl2] [Fe(CN)6]4- [Fe(OH2)6]2+ [Zn(CN)4]2- [Cd(NH3)4]2+ [Cu(CO)5] [CuCl5]3- [Fe(EDTA)]2- [Pt(en)2]2+
What is the systematic name for each of the following coordination compounds (a) Zn[Ni(OH).] (Ni: Nickel)...
What is the systematic name for each of the following coordination compounds (a) Zn[Ni(OH).] (Ni: Nickel) (b) (Nb(H2O)2(en)(Br)2](CO3) (Nb: Niobium ) (C) [V(NH3)Br2(H2O) (C204)]NO3 (Oxalate anion: C2042, V: Vanadium) (d) [Mn(en)l2(NO3)2]2(SO4) (Mn: Manganeze)
do all Question 3 1 pts The complex [Os(bpy)2C12]* can exist as how many geometric and...
do all
Question 3 1 pts The complex [Os(bpy)2C12]* can exist as how many geometric and optical isomers (bpy = 2,2-bipyridine)? 03 O 5 Question 4 1 pts Question 5 1 pts The lowest energy absorption band (which corresponds to 10Dq) for [V(OH2)6]2+ occurs at 12,300 cm-'. The crystal field stabilisation energy (CFSE) for [V(OH2)]2+ is approximately 4,920 cm 7,380 cm 9,840 cm 12,300 cm 14,700 cm 1 pts Question 6 Question 6 1 pts Arrange the ligands in the...
4- What is the systematic name for each of the following coordination compounds? (a) Zn[Ni(OH)4] (Ni:...
4- What is the systematic name for each of the following coordination compounds? (a) Zn[Ni(OH)4] (Ni: Nickel) (b) (Nb(H2O)2(en)(Br)2](CO3) (Nb: Niobium ) (c) [V(NH3)Bra(H2O)(C20)JNO (Oxalate anion: CO2, V: Vanadium) (d) [Mn(en)la(NO3)2]2(SO4) (Mn: Manganeze)
Part A Which of the following pairs of coordination compounds or complex ions are examples of ionization isomers? [Fe(NH3)2(H20)4]Cl2 and [Fe(NH3)4(H20)2Cl2 [Cu(CO)gBr]CI and [Cu(CO), CIJBr [MnCl3Br]2- and [MnCIBr312- [Fe(NH3)2(H20)4]C12 and [Fe(NH3)2(H20)4]Br2 [Fe(CO)NO12+ and [Fe(CO) ONO]2+ Submit Previous Answers Request Answer Part A Identify the isomers that have ligands that coordinate to a metal with different donor atoms. stereoisomers cis-trans isomers linkage isomers O coordination isomers O optical isomers Submit Request Answer Which of the following is a type of constitutional...
Circle the pairs of compounds that are isomers of each other: (a) [Co(en)_3]Cl_3 and [Co(en)_3]Br_3 (b) [Co(H_2O)_4 Br_2]Cl and [Co(H_2O)_4BrCl]Br (c) [Cr(H_2O)_2(CO_3)_2]^2+ and [Cr(H_2O)_2(CO)_2(O_2)_2]^2+ (d) trans-[Pt(NH_3)_2Cl_2] and [Pt(NH_3)_3Cl]Cl Circle the appropriate description of the distinction between "geometric isomers" and "optical isomers": (a) Geometric isomers have a different set of bonds. optical isomers have the same set of bonds. (b) Geometric isomers differ in the spatial arrangement of bonds. In optical isomers the arrangement of bonds is the same. (c) Geometric...
What is the systematic name for each of the following coordination compounds (a) Zn[Ni(OH).] (Ni: Nickel) (b) (Nb(H2O)2(en)(Br)2](CO3) (Nb: Niobium ) (C) [V(NH3)Br2(H2O) (C204)]NO3 (Oxalate anion: C2042, V: Vanadium) (d) [Mn(en)l2(NO3)2]2(SO4) (Mn: Manganeze)
do all
Question 3 1 pts The complex [Os(bpy)2C12]* can exist as how many geometric and optical isomers (bpy = 2,2-bipyridine)? 03 O 5 Question 4 1 pts Question 5 1 pts The lowest energy absorption band (which corresponds to 10Dq) for [V(OH2)6]2+ occurs at 12,300 cm-'. The crystal field stabilisation energy (CFSE) for [V(OH2)]2+ is approximately 4,920 cm 7,380 cm 9,840 cm 12,300 cm 14,700 cm 1 pts Question 6 Question 6 1 pts Arrange the ligands in the...
4- What is the systematic name for each of the following coordination compounds? (a) Zn[Ni(OH)4] (Ni: Nickel) (b) (Nb(H2O)2(en)(Br)2](CO3) (Nb: Niobium ) (c) [V(NH3)Bra(H2O)(C20)JNO (Oxalate anion: CO2, V: Vanadium) (d) [Mn(en)la(NO3)2]2(SO4) (Mn: Manganeze)
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