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Show the mechanisms and reaction energy diagrams for the transformation with potassium tert-butoxide leading to trans-2-heptene....

  1. Show the mechanisms and reaction energy diagrams for the transformation with potassium tert-butoxide leading to trans-2-heptene. Please include a drawing of the anti-periplanar transition state. Would the transition state energy for the reaction leading to cis-2-heptene be higher or lower? Please explain your hypothesis.

  2. Would the product ratio (trans-2-heptene / 2-cis-2-heptene change if you run our experiment at room temperature instead of reflux temperature? Please explain your hypothesis.

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Answer #1

Eliminatiom reaction is highle dependent on temperature and its product distribution is affected by variation of reaction temperature.

Trans product is more stable than cis.

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