Question

Indicate whether or not each of the following ionic compounds will undergo hydrolysis and predict whether...

Indicate whether or not each of the following ionic compounds will undergo hydrolysis and predict whether the resulting solution pH will be acidic, basic, or indeterminate (both ions undergo hydrolysis).

(a)    PbCr2O7

acidic hydrolysis

basic hydrolysis   

indeterminate hydrolysis

no hydrolysis


(b)    MgCl2

acidic hydrolysis

basic hydrolysis  

indeterminate hydrolysis

no hydrolysis


(c)    NaF

acidic hydrolysis

basic hydrolysis   

indeterminate hydrolysis

no hydrolysis


(d)    CoCO2

acidic hydrolysis

basic hydrolysis

indeterminate hydrolysis

no hydrolysis

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Answer #1

a) PbCr2O7 is a salt of strong acid H2Cr2O7(dichromic acid) and weak base Pb(OH)2.

Thus the anion( basic ) undergoes basic hydrolysis giving an acidic solution.

b) MgCL2 is a salt of weak base Mg(OH)2 and strrong acid , thus the basic( anionic) hydrolysis giving acidic solution.

c) NaF is a salt of strong base NaOh and weak acid HF , thus cationic(acidic) hydrolysis giving basic solution.

d) CoCO3 is a salt of weak baseCo(OH)2 and weak acid H2CO3 . thus both anion and cation (basic and acidic) hydrolysis takeplace.

Thus indeterminate hydrolysis.

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