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how can you use pH to separate Ni(II) ions from Hg(II) ions? The solubility product of...

how can you use pH to separate Ni(II) ions from Hg(II) ions?

The solubility product of HgS is roughly 2 x 10-53 and that of NiS is 3 x 10-19. If we wanted to separate these two ions by a differential precipitation, how might I do that?

Consider the use of hydrosulfuric acid as your precipitating agent. Look up the Ka1 and Ka2 for hydrosulfuric acid and use those values to perform a calculation showing the pH range needed to separate the two metal ions.

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