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Find the limiting reagents when 50mL of 2.00M HCl is mixed with 50mL of 2.00M NaOH...

Find the limiting reagents when 50mL of 2.00M HCl is mixed with 50mL of 2.00M NaOH and when 50mL of 0.67M H3PO4 is mixed with 50mL of 2.00M NaOH. Why is the concentration of H3PO4 solution 0.67M and that of HCl 2.00M? Find the theoretical standard molar enthalpies for these neutralization reactions using the standard molar enthalpies of formation.

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