

13. (20 points) Outline syntheses for each of the following compounds starting from ethyl acetoacetate and...
13. (20 points) Outline syntheses for each of the following compounds starting from ethyl acetoacetate and any other reagents as needed: 0 0 A DEL
outline labratory syntheses of each of the following compounds
starting with benzene and any other reagents
Outline laboratory syntheses of each of the following compounds, starting with benzene and any other reagents. (c) CI (a) p-nitrotoluene (b) p-dibromobenzene (c) p-chloroacetophenone (d) m-nitrobenzenesulfonic acid (e) p-chloronitrobenzene (f) 1,3,5-trinitrobenzene (g) 2,6-dibromo-4-nitrotoluene
Propose syntheses of each of the following compounds, from the given starting material and any other needed reagents. » O- CH2OH from O con b) CH3CCHz from CH3CH=CH2 ОН • OCHGHs from O-Br
14. Starting with an appropriate alkyl halide and using any
other needed reagents, outline the syntheses of each of the
following. When alternative possibilities exist for a synthesis,
you should choose the one that gives the better product. Indicate
whether each reaction follows an SN1 or SN2 reaction mechanism.
14. Starting with an appropriate alkyl halide and using any other needed reagents, outline the syntheses of each of the following. When alternative possibilities exist for a synthesis, you should choose...
need D,E & G. outline a reaction sequence for synthesis of each
of the following compounds from the indicated starting material
& any other organic or inorganic reagents needed.
Outline a reaction sequence for synthesis of each of the following compounds from the indicated starting material and any other organic or inorganic reagents needed. (a) 0 0 0 он OEt он ,EUA 853 PROBLEMS NH+ (g) O OEt OE
Outline a reaction sequence for synthesis of each of the following...
3 e f g
3. Suggest efficient syntheses for the following compounds, starting from the compound indicated and any other needed reagents. (98 pts) e) benzonitrile (C HsCEN) starting from benzene. (f) octanoic acid, from 1-hexanol. (g) phenol, from aniline (CsHsNH:).
3. Propose reasonable syntheses of each of the following compounds from the given starting materials. You may use any other readily available alkyl halides, solvents and reagents as necessary. More than one step is necessary. Show all intermediates, reactions, reagents and conditions clearly. It is not necessary to show the mechanism. HCECH HCECH , X HCECH HC=CH M H OHC (30 marks)
20 2) Suggest efficient syntheses for two of the following four compounds from the available starting material(s), specifying necessary reagents for each step. NO OH NH from NH Br b) from gary lio from from CHI
question 1: Propose a synthesis of the compound below on the
left from ethyl acetoacetate (ethyl 3-oxobutanoate). You may use
any of the reagents in the table.
question 2:
Each of the compounds below is treated with a large molar excess
of D2O containing a catalytic amount of NaOD. When this
is done all of the acidic hydrogens are exchanged for deuteriums.
Indicate the number of hydrogens exchanged on each compound.
question 3: Indicate whether the compounds below undergo
racemization...
Show how you would use Grignard syntheses to prepare the
following alcohols from the indicated starting materials and any
other necessary reagents. Draw the Grignard reagent and any other
organic reagents needed.
11 RUVIUWI Constans i Pendulu Part F Show how you would use Grignard syntheses to prepare the following alcohols from the indicated starting materials and any other necessary reagents. Draw the Grignard reagent and any other organic reagents needed. ОН -C-CH CH, from C-OCH.CH Draw the molecules on...