

1.- Define what are complex ions 2.- Using NiCl as a reactant look in a book...
1) Consider the molecule [Nicl]. It is tetrahedral geometry and Ta symmetry Consider the sigma-bonding and determine a reducible representation for the molecule. Determine the irreducible representation. Draw a qualitative molecular orbital diagram with electrons and symmetry labels. Consider carefully the oxidation state of the metal and ligands and fill in electrons thoughtfully. You will only utilize the 3d orbitals on Nickel, not the 4s or 4p. The ligand group orbitals of the chlorine ligands should be lower in energy...
2 A molecular orbital diagram for a tetrahedral transition metal complex is shown below. Show how the electrons occupy the molecular orbitals in the diagram for each complex (a)-(g). Why are low-spin, tetrahedral transition metal complexes rare? (a) [MnBra (d) [CuCl (b) [CrC (e) [NICI (c) IMnO (OsO (g) MoF ΔΤ e+t a+t 4L a (b) Identify the bonding, anti-bonding, and non-bonding orbitals in this diagram. M
1- Draw the molecular orbital diagram of transition metal ion in high-spin Mn(H2O)4(OH)2 complex, also determine the number of unpaired electron. 2- Draw the molecular orbital diagram of transition metal ion in low-spin [Cr(en)2(NH3)2].Cl2 complex, also determine the number of unpaired electron. 3- Draw the molecular orbital diagram of transition metal ion in high-spin K.[Mn(CO)3(OH)3] complex, also determine the number of unpaired electron.
20 What is the reason why many complex ions es (a) The metal's d b) The metal ion (e) The ligands create a vegative crystal fie (d) The splitting lbsit magnetic properties rbitals get split into twe diftferent often has unpaired d electrons energy ? is larger in some complex ions than in others. complex ions have a distinctive Crystal Field Spliting Diagram. Wh? (a) (b) Octahedral The six ligands that ions are the only commplex ions whone ligands are...
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can't solve this question of coordination chemistry, could someone
hlep me please
Exercise 1: 1. What kind(s) of interaction between the ligand and the metal ion is(are) considered in the crystal field approach? 2. Give and justify the degeneracy lifting for a tetrahedral complex. Would it be the same for an octahedral complex? 3. Let us consider hexaaquacopper(II) ion. Justify the elongation of two opposite Cu-O bonds (along z for example) compared to the other four Cu-O bonds using...
During the formation of a coordination compound, the metal acts as a .A) Bronsted acid B) Arrhenius acid C) Bronsted base D) Lewis base E) Lewis acid 2) The coordination sphere of a complex consists of. A) the central metal ion only B) coordination and steric numbers C) the ligands D) the primary and secondary valencies E) the central metal ion and the ligands bonded to it 3) How many d electrons are in the cobalt ion of K_3[Co(CN)_6]? A)...
[TI(H20)is an octahedral complex. (9 pts) 3. Name this complex. b. How many d electrons does it have? Sketch the d-orbital diagram for the complex. Label the energy levels (t and e and a. c. each of the d-orbitals. d. A is 3.99 x 10-19 ] (per photon). What is the value of A in kl/mol? e. Calculate the wavelength of light (nm) needed to excite an electron from the tag to the e, orbital. f. What color of the...
ANSWER ALL QUESTIONS PLEASE 1. What are the characteristic electron configurations of transition metals? 2. What is the general trend in atomic size across a transition metal series? 3. Which electrons, 3d or 4s, have the lowest ionization energies in a transition metal? 4. What is the general trend of the reducing strength across a transition metal series? 5. Why do transition metals have similar chemical properties? 6. Name four transition metals that are essential to the biological system. 1. Write the...
can
anyone please confirm my answers for 5&6? And can you explain
how to fill in the electrons for 7? Please and Thank you.
5. The values of A, for some coordination complexes are given below. (a) [Fe(ox)) --- 14,100 cm-1 (ox-oxalato ligand-----weak ligand] (b) [Fe(CN).-----35,000 cm ©) [Fe(CN)6]* -----33,800 cm (1) Explain reason(s) why A. of complex (a) and (b) are different (ii) Explain reason(s) why 4, of complex (b) and (c) are different 6. Answer the following questions...
What is the charge on the anion in the coordination compound K2[Pt(NO2)2Cl2]? The pair of brackets “[‘” and “]” indicate the presence of a metal complex, and this collection of atoms/ions can be thought of as one molecular species (in this case an anion). Platinum is at the center of the complex with NO2− (through the N) and Cl− forming coordinate bonds with the Pt. Draw the Lewis structures of NO2− (nitro) and Cl−. Circle the electron pair in each...