Question

Rank the crystal lattice structures in order of decreasingefficiency of space in the structure. 1.Simple cubic...

Rank the crystal lattice structures in order of decreasingefficiency of space in the structure.
1.Simple cubic
2.Body centered cubic
3.Face centered cubic
4.Hexegonal close packed
I know simple cubic is the least effcient, and i figured itwhould be HCP-FCC-BCC-Simple cubic, but its not..
help please!! thanks
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Answer #1
Concepts and reason

Matter exists in various forms such as gaseous state, liquid state, and solid state. In solid state, the constituent particles are arranged very closely. Solids mainly exist in two forms, such as amorphous solids and crystalline solids.

Crystalline solid has rigidity, incompressibility, and specific shape. The crystalline solids are ordered by arrangement of atoms, ions, or molecules.

Fundamentals

There are seven major types of crystals depending on the shape of the crystal.

• Cubic

Tetragonal

Hexagonal

Rhombohedral

Orthorhombic

Monoclinic

Triclinic

In crystallography, the packing efficiency of crystals is calculated by atomic packing factor. This is defined as the fraction of volume or space occupied by atom in a unit cell.

Volume of atoms in unit cell
Volume of unit cell

The known values of the atomic packing factor or packing efficiency of crystal structure is as follows.

For simple cubic (SC):

The atomic packing factor for SC = 0.52 or 52%

For body-centered cubic (BCC):

The atomic packing factor for BCC = 0.68 or 68%

For face-centered cubic (FCC):

The atomic packing factor for FCC = 0.74 or 74%

For hexagonal close packing (HCP):

The atomic packing factor for HCP = 0.74 or 74%

The fraction of free space or volume of SC:

= 100%-52%
= 48%

The fraction of free space or volume of BCC:

= 100%-68%
=32%

The fraction of free space or volume of FCC

= 100%-74%
= 26%

The fraction of free space or volume of HCP

= 100%-74%
= 26%

Therefore, the order of decreasing efficiency of space in the given structure is HCP = FCC> BCC>SC

Ans:

The decreasing order of space in the given crystal lattice structures is HCP = FCC > BCC>SC.

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