What are the most commonly used methods to form epoxides and what are their shortcomings? What...
What are the most commonly used methods to form epoxides and what are their shortcomings?
What is the purpose of the slow addition of the epoxidizing agent to the alkene?
Homework Answers
1. Peroxyacid or peracid are most commonly used for epoxidation reaction for example peracetic acid, m-CPBA etc.
2. Hydrogen peroxide also most commonly using for epoxidation reaction.
3. Shortcomings of epixidaepox is reaction should be dry otherwise epoxide will get quenched and rectione don't give epoxide.
4. Alkene should be electron rich system then reaction will be fast, if there is electron withdrawing group on alkene then reaction don't move.
5. Epoxidation reaction exothermic reaction so we need do addition of epoxidizing reagent slowly to avoid formation of impurities and to avoid epoxide opening.
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