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Potential (mv) ml AgNO3 If this sketch shows a potentiometric titration of KI and KCl with AgNO3, draw a circle for the endpo
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Answer #1

1. As the Ksp of AgI is much lower than that of AgCl. Hence, we will observe first the endpoint of AgI and then AgCl. You have correctly marked the endpoints of the KI (circle) and KCl (square) already.    

2. The KI titration endpoint is not observed at the midpoint where we expect to be. But it will be observed below the midpoint due to the incomplete formation of the precipitate of AgI at the midpoint. Due to the involvement of the AgCl precipitation equilibria there.   

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