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In the case of addition of hydrogen chlorid onto 1-hexyne, the main product is: a. 1,1-dichlorohexane...
8. Show how you would convert 1,1-dichlorohexane into 1-hexyne. All the appropriate chemical equations must be shown. (4 pts) 9. Give examples which show the effect of double dehydrohalogenation of both geminal and vicinal dihalides. The reagents must be included. (4 pts)
What is the name of the product of the reaction?
(please explain, show work)
a. 1,1-dibromo-5-methylhexane
b. 1,2-dibromo-5-methylhexane
c. 1,2-dibromo-5-methyl-1-hexene
d. 2,2-dibromo-5-methylhexane
e. 1,1,2,2-tetrabromo-5-methylhexane
2 equivalents F it HBr is
Show all products of the addition methods from these sections to 1-hexyne and 2-hexyne. a) 1 eq HCl b) 1 eq Br2 c) 2 eq Br2 d) Hydroboration-oxidation
Which of these is a structural isomer pair? A. heptane and 2,3-dimethylpentane B. 1,1-dichloro-2-methylpropane and 2,3-dichlorohexane C. 1,2-dichloropentene and 2,3-dibromopentene D. pentene and 2-methylbutane E. all of the above
Write the structure of the major organic product isolated from the reaction of 3-hexyne with (a) Hydrogen (2 mol), platinum (f) Chlorine (2 mol) (b) Hydrogen (1 mol), Lindlar palladium (g) Aqueous sulfuric acid, mercury(II) sulfate (C) Hydrogen chloride (1 mol) (h) Ozone followed by hydrolysis (d) Hydrogen chloride (2 mol) (e) Chlorine (1 mol)
a)
b)
What is the final major product expected for the following reaction sequence? 1) H2, Ni2B (P-2)2) C2 CCI4 meso-3,4-dichlorohexane ()-3,4-dichlorohexane (R)-3-chlorohexane 2,3-dichloro-3-hexene (S)-3-chlorohexane o 0 What is the final major product expected for the following reaction sequence? 1) Na, NH3() 2) Br2 CCl meso-3,4-dibromohexane 2,3-dibromo-3-hexene (t)-3,4-dibromohexane (S)-3-bromohexane (R)-3-bromohexane
Find all pure strategy Nash Equilibria in the following games a.) Player 2 b1 b2 b3 a1 1,3 2,2 1,2 a2 2,3 2,3 2,1 a3 1,1 1,2 3,2 a4 1,2 3,1 2,3 Player 1 b.) Player 2 A B C D A 1,3 3,1 0,2 1,1 B 1,2 1,2 2,3 1,1 C 3,2 2,1 1,3 0,3 D 2,0 3,0 1,1 2,2 Player 1 c.) Player 2 S B S 3,2 1,1 B 0,0 2,3
QUESTION 1 Hydrogenation of 3-hexyne with Pd catalyst gives: O a. hexane b.(E)-3-hexene OC. (Z)-3-hexene d. 3-hexanol QUESTION 2 Reaction of ethanol with metallic Na belongs to: a. acid-base reactions b. Sn2 reactions c. E1 reactions O d. redox reactions QUESTION 3 If 1-hexyne is subjected first to Lindlar's catalyst and hydrogen, and then the formed product is treated with HBr in the presence of radicals, the ultimate product is: a. 1-bromohexene b.2-bromohexane c. dodecane d. 1-bromohexane
Which is the correct formula for C[i,j] in product of n x n matrices A and B. explain A (A[1,1] + A[2,2] + ... + A[n,n]) + (B[1,1] + B[2,2] + ... + B[n,n]) B (A[1,1] + A[2,2] + ... + A[n,n]) x (B[1,1] + B[2,2] + ... + B[n,n]) C (A[1,1] x A[2,2] x ... x A[n,n]) x (B[1,1] x B[2,2] x ... x B[n,n]) D (A[1,1] x A[2,2] x ... x A[n,n]) + (B[1,1] x B[2,2] x ......
5. a) Draw the major 1,2-addition product and the major 1,4-addition product of each of the following reactions. Label each product as either the 1,2-addition product or 1,4-addition product and as either the thermodynamic or kinetic product. (12 pts) H" catalyst H catalyst b) Consider the reaction of a nucleophile with conjugated carbonyl. Provide an example of a nucleophile that would favor the 1,2-addition product and explain why. Provide an example of a nucleophile that would favor the 1,4-addition product...