Question

. The peaks for 1.22. 21.16 The molecular ion for compound D does not appear in its mass spectrum the important fragments from the molecular ion, however, are clearly seen in Figure 2 Assign a structure to compound D Compound D 100 80 60 40 20 120 140 160 100 (Adapted from Stenhagen et al. Reprinted by permission.) 20 40 60 80

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Answer #1

The compound has peak at 79 and 81 m/z in equal intensity might be due to bromide ion

The compound has base peak at m/z 43 might be due to isopropyl cation

The compound has intense peak at 15 is due methyl cation

Therefore the structure of the compound might be isopropyl bromide

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